[Rh(norbornadiene)Cl(PiBu3)] | 1429989-52-5

• 英文名称: [Rh(norbornadiene)Cl(PiBu3)]
• 英文别名: [Rh(norbornadiene)Cl(PⁱBu₃)]；[Rh(NBD)Cl(PⁱBu₃)]
• CAS: 1429989-52-5
• 化学式: C₁₉H₃₅ClPRh
• 分子量: 432.819
• InChiKey: SKLNOCBEMBPDGU-XDWRCRRRSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  di-μ-chlorobis(norbornadiene)dirhodium(I) 、 三异丁基磷烷 以 二氯甲烷 为溶剂， 反应 2.0h， 以75%的产率得到[Rh(norbornadiene)Cl(PiBu3)]
  参考文献：
  名称：

  The influence of phosphine cone angle on the synthesis and structures of [Rh(PR3)(Binor–S)]+ complexes that show C–C sigma interactions

  摘要：

  Complexes that show C-C center dot center dot center dot Rh sigma interactions have been synthesized and characterised by NMR spectroscopy and X-ray diffraction: [Rh(PR3)(Binor-S)}[BAr4F], R = (PBu2Me)-Bu-t, PCy(2)Fh; Ar = C6H3(CF3)(2), Binor-S = 1,2,4,5,6,8-dimetheno-S-indacene. These studies, in concert with previously published work, show that there is a rather narrow window of phosphine steric profile that supports the isolation of these interesting complexes, with the phosphine cone angle lying between 160 degrees and 170 degrees. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.09.013