Os₃(CO)₉(μ-CO)(μ₃-S) | 88746-45-6

• 英文名称: Os₃(CO)₉(μ-CO)(μ₃-S)
• 英文别名: [Os3(CO)10(μ-S)]；Os3(CO)9(μ3-CO)(μ3-S)
• CAS: 88746-45-6
• 化学式: C₁₀O₁₀Os₃S
• 分子量: 882.77
• InChiKey: IVURLNBADLUSBK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  Os₃(CO)₉(μ-CO)(μ₃-S) 以 正己烷 为溶剂， 以44%的产率得到Os6(CO)17(μ4-S)2
  参考文献：
  名称：

  Adams, Richard D.; Horváth, István T.; Kim, Hoon-Sik, Organometallics, 1984, vol. 3, # 4, p. 548 - 552

  摘要：

  DOI：
• 作为产物：
  描述：

  {Os3(CO)10(μH)(μSC6H5)} 以 正己烷 为溶剂， 以41%的产率得到Os₃(CO)₉(μ-CO)(μ₃-S)
  参考文献：
  名称：

  Adams, Richard D.; Horváth, István T.; Kim, Hoon-Sik, Organometallics, 1984, vol. 3, # 4, p. 548 - 552

  摘要：

  DOI：

文献信息

• Metal cluster-induced desulphurization of N-(p-methoxybenzoyl)-S-benzoylsulphenamide. Crystal and molecular structures of [Os6(CO)20(μ4-S)(MeCN)]
  作者：Siu-Ming Lee、Kung-Kai Cheung、Wing-Tak Wong

  DOI：10.1016/0022-328x(95)05726-6

  日期：1995.11

  Reaction of N-(p-methoxybenzoyl)-S-benzoylsulphenamide1 with [Os3(CO)10(MeCN)2] at room temperature gives Os3(CO)10(μ3-S)]2 and [Os6(CO)20(μ4-S)(MeCN)]3 in moderate yield. The crystal structure of 3 has been determined. Complex 2 is an intermediate in the formation of 3. Complex 3 undergoes dissociation of CO to give [Os6(CO)19(μ3-S)] and [Os5(CO)15(μ4-S)].

  N-的反应（p甲氧基苯甲酰基）-S- benzoylsulphenamide 1与[O的3（CO）10（MeCN中）2 ]在室温下使O的3（CO）10（μ 3 -S）] 2和[O的6（ CO）20（μ 4 -S）（MeCN中）] 3在适中的产率。已经确定了3的晶体结构。络合物2是形成3的中间体。配合物3经历一氧化碳分解，生成[Os 6（CO）19（μ 3 -S）]和[O的5（CO）15（μ 4 -S）]。
• A dual signal amplification nanosensor based on SERS technology for detection of tumor-related DNA
  作者：Duo Lin、Tianxun Gong、Sufang Qiu、Qiong Wu、Ching-Yu Tseng、Kien Voon Kong、Guannan Chen、Rong Chen

  DOI：10.1039/c8cc07461e

  日期：——

  A dual signal amplification array based on SERS is developed by photo-triggered release of probes for reliable and sensitive DNA detection.

  基于SERS的双信号放大阵列是通过光触发释放探针来可靠和敏感地检测DNA的。
• Cluster condensations. The dimerization of [Os3(CO)9(μ3-CO)(μ)3-S)]
  作者：Richard D. Adams、Jin-Guu Wang

  DOI：10.1016/s0277-5387(00)86258-0

  日期：1989.1

  UV irradiation of [Os3(CO)9(μ3-CO)(μ3-S)] (1) under a CO atmosphere has yielded the new hexaosmium cluster complex [Os 6(CO)20(μ3-S)(μ4-S)] (2) in 13% yield (30% based on the amount of 1 consumed). Compound 2 is a dimer of 1 based on its formula, but its structure is considerably different. Compound 2 was characterized by a single-crystal X-ray diffraction analysis. Crystal data: Os6S2O20C20·1/3CHCl3·H2O

  的紫外线照射了[Os 3（CO）9（μ 3 -CO）（μ 3 -S）]（1）在CO气氛已经产生了新的hexaosmium簇络合物[O的下6（CO）20（μ 3 -S） （μ 4 -S）]（2）在13％的收率（基于所述的量30％1消耗）。化合物2基于其分子式为1的二聚体，但其结构有很大不同。化合物2通过单晶X射线衍射分析来表征。晶体数据：Os 6 S 2 O 20 C20 ·1 / 3CHCl 3 ·H 2 O，中号= 1759.0，菱形，- [R（148号），一个= 43.333（9），C ^ = 10.203（1）埃，V = 16592（9）埃3，d Ç =3.17克厘米-3，ž = 18，λ（莫-K α）= 0.71069埃（石墨单色）μ=202.4厘米-1。方法：MITHRIL，差分傅立叶，全矩阵最小二乘法。的2754个反射细化[ ˚F 2 ⩾3σ（˚F 2）]，（1⩽2θ⩽43°），得到[R和-
• Nucleophilic ring opening of bridging thietanes in open triosmium cluster complexes
  作者：Richard D. Adams、Judy A. Belinski

  DOI：10.1021/om00043a035

  日期：1992.7

  The complexes Os3(CO)9(mu-3-S)[mu-SCH2CMe2CH2] (1) and Os3(CO)9(mu-S)[mu-3-SCH2CH2CH2] (2) were obtained from the reactions of Os3(CO)10(mu-3-S) with 3,3-dimethylthietane (DMT) and thietane, respectively, at -42-degrees-C in the presence of Me3NO. Compound 1 was characterized by a single-crystal X-ray diffraction analysis and was found to contain a DMT group bridging two of the nonbonded metal atoms in the open cluster of three metal atoms by using both lone pairs of electrons on the sulfur atom. Compound 1 reacted with bis(triphenylphosphine)nitrogen(1+) chloride ([PPN]Cl) at 25-degrees-C to yield the salt [PPN]Os3(CO)9(mu-SCH2CMe2CH2Cl)(mu-3-S)] (3; 76%), in which the chloride ion was added to one of the methylene groups of the DMT ring in a process that caused the ring to open by cleavage of one of the carbon-sulfur bonds. A 4-chloro-3,3-dimethylpropanethiolate ligand bridges the open edge of the anionic triosmium cluster. Compound 3 was converted to the neutral complex (Os3(CO)9[mu-SCH2CMe2CH2Cl](mu-3-S)(mu-H) (4) by reaction with HCl at 25-degrees-C. Compound 4 is structurally similar to 3, except that it contains a hydride ligand bridging one of the two metal-metal bonds. Compounds 1 and 2 react with HCl in CH2Cl2 solvent to yield the neutral compounds 4 and Os3(CO)9[mu-SCH2CH2CH2Cl](mu-3-S)(mu-H) (5) in 89% and 90% yields, respectively, in one step. Crystal data for 1: space group P2(1)/c, a = 9.690 (2) angstrom, b = 18.813 (4) angstrom, c = 13.932 (2) angstrom, beta = 109.41 (1)-degrees, Z = 4, 2112 reflections, R = 0.027. Crystal data for 3: space group P1BAR, a = 17.309 (2) angstrom, b = 17.768 (2) angstrom, c = 9.558 (1) angstrom, alpha = 104.99 (1)-degrees, beta = 103.64 (1)-degrees, gamma = 104.04 (1)-degrees, Z = 2, 3825 reflections, R = 0.025. Crystal data for 4: space group P1BAR, a = 12.500 (2) angstrom, b = 14.108 (2) angstrom, c = 6.4657 (6) angstrom, alpha = 102.380 (9)-degrees, beta = 99.20 (1)-degrees, gamma = 86.87 (1)-degrees, Z = 2, 2111 reflections, R = 0.024.
• Carbon-sulfur bond cleavage with a loss of stereochemistry in the ring opening of trans-2,4-diphenylthietane by Os3(CO)10(NCMe)2
  作者：Richard D. Adams、Michael P. Pompeo

  DOI：10.1021/om00037a024

  日期：1992.1

  The reaction of Os3(CO)10(NCMe)2 with trans-2,4-diphenylthietane (2,4-DPT) at 25-degrees-C resulted in the formation of two isomers, cis- and trans-Os3(CO)10[mu-SC(H)PhCH2C(H)Ph] (1), in a combined yield of 76%. The cis product was characterized by single-crystal X-ray diffraction analysis and was found to contain a thiametalladiphenylcyclopentane ring formed by the opening of the thietane ring. The cis and trans isomers differ in the orientation of their phenyl substituents. The isomers are formed in approximately equal amounts in the early stages of the reaction, but the trans isomer subsequently slowly isomerizes to the cis isomer. The observed loss in stereochemistry at the carbon center is attributed to a stepwise ring-opening mechanism. When compound 1 was heated to 97-degrees-C under a CO atmosphere, five compounds were formed: Os3(CO)10[mu-SC(H)PhC(H) = C(H)Ph[(mu-H) (2) (22%), Os2(CO)7[mu-SC(H)(C6H4)CH2CH2Ph] (3) (11%), Os3(CO)11[mu-SC(H)PhCH2C(H)Ph] (4) (39%), H2Os6(CO)17(mu(3)-S)(mu(4)-S) (5) (a trace amount), and Os3(CO)12. Compounds 3 and 5 and the known compound Os3(CO)9(mu(3)-CO)(mu(3)-S) (6) were obtained in better yields by heating 2 to 125-degrees-C in octane solvent. Compounds 2-4 were characterized by IR, H-1 NMR, and single-crystal X-ray diffraction analyses. Compound 2 is an isomer of 1 and contains a diphenylpropenethiolate and hydride ligand formed by a ''beta-elimination'' transformation of the ring system in 1. The mechanism of this transformation was not established. Compound 3 contains only two metal atoms and an ortho-metalated phenyl ring. Compound 4 is a CO adduct of 1 formed by the cleavage of the sulfur-bridged metal-metal bond. Crystallographic data are as follows. cis-1: space group P2(1)/c, a = 8.674 (2) angstrom, b = 35.09 (1) angstrom, c = 9.449 (2) angstrom, beta = 106.41 (1)-degrees, Z = 4, 2053 reflections, R = 0.033. 2: space group C2/c, a = 13.845 (2) angstrom, b = 14.545 (4) angstrom, c = 28.907 (6) angstrom, beta = 98.88 (1)-degrees, Z = 8, 2519 reflections, R = 0.027. 3: space group P2(1)/c, a = 8.337 (1) angstrom, b = 17.311 (4) angstrom, c = 16.409 (3) angstrom, beta = 100.82 (1)-degrees, Z = 4, 2299 reflections, R = 0.036. 4: space group P1BAR, a = 14.319 (2) angstrom, b = 17.794 (5) angstrom, c = 12.257 (4) angstrom, alpha = 106.69 (2)-degrees, beta = 90.74 (2)-degrees, gamma = 82.56 (2)-degrees, Z = 4, 4020 reflections, R = 0.041.