strontium monofluoride | 13569-27-2

• 英文名称: strontium monofluoride
• CAS: 13569-27-2
• 化学式: FSr
• 分子量: 106.618
• InChiKey: GXLMLAGMLTWIOF-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.04
• 重原子数：
  2.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  strontium fluoride 以 neat (no solvent) 为溶剂， 生成 strontium monofluoride
  参考文献：
  名称：

  The fine and magnetic hyperfine structure of ⁸⁷SrF in its X ²Σ⁺ state

  摘要：

  A molecular beam rf–optical double resonance experiment was performed on 87SrF in its naturally occurring abundance ratio. The natural occurring abundances of the strontium isotopes are 86Sr (9.8%), 87Sr(7.02%) and 88Sr (82.5%). Numerous magnetic dipole allowed transitions between ρ-doublets in the X 2Σ+ state were measured to an accuracy of 3 kHz. The observed spectra were analyzed in terms of an effective Hamiltonian which includes the magnetic hyperfine and electric quadrupole interactions arising from the 87 Sr (I=9/2) and 19F (I=1/2) nuclei. The extracted spectroscopic hyperfine parameters were interpreted in terms of a simple molecular orbital picture for the electronic nature of the X 2Σ+ state. A comparison is made to previous results for the more abundant 86SrF and 88SrF isotopic forms.

  DOI：

  10.1063/1.459622

文献信息

• Optical-optical double-resonance spectroscopy of SrF: The F 2Σ+-B 2Σ+ and G 2Π-B 2Σ+ systems
  作者：C. Nitsch、J.O. Schröder、W.E. Ernst

  DOI：10.1016/0009-2614(88)80288-4

  日期：1988.7

  Sub-Doppler optical-optical double-resonance spectra of SrF were recorded using two single-mode cw dye lasers. Via the intermediate state B 2Σ+, the F 2Σ+ and G 2Π states were observed in the 32000 to 35000 cm−1 region above the ground state. The (1, 0), (2, 0), and (3, 0) bands of the F 2Σ+-B 2Σ+ transition and the (0, 0) band of the G 2Π-B 2Σ+ transition were rotationally analyzed. Rotational and vibrational

  使用两个单模连续染料激光器记录了SrF的亚多普勒光学双共振光谱。经由中间状态B 2 Σ +，则F 2 Σ +和G 2 Π状态在32000至35000厘米观察-1区域上方的基态。的（1,0），（2,0），和（3，0）的F频带2 Σ + -B 2 Σ +过渡和G的（0，0）带2 Π-B 2 Σ +过渡进行了旋转分析。为F转动和振动常数2 Σ +报告了G 2π态和G 2Π态的旋转常数。
• Comparison of reagent translation and vibration on the dynamics of the endothermic reaction Sr+HF
  作者：Arunava Gupta、David S. Perry、Richard N. Zare

  DOI：10.1063/1.439038

  日期：1980.6

  The endothermic reaction Sr+HF(v=0)→SrF+H has been studied as a function of collision energy (4–14 kcal/mole) using a crossed beam geometry in which a seeded HF beam intersects a thermal Sr beam. At the same total energy this reaction is compared to the Sr+HF(v=1, J=1) reaction carried out under beam-gas conditions with a pulsed HF laser as the excitation source. In both cases the SrF products are detected by laser induced fluorescence. Using the Ba+HF→BaF+H reaction as an internal reference, the cross section of the Sr+HF(v=1) reaction is found to be 1–10 times greater than for the Sr+HF(v=0) reaction when the same total energy is supplied as reagent translation. Product internal energy distribution and total relative cross sections as a function of collision energy are also measured. Phase space calculations are able to reproduce most of these results. This agreement and other arguments suggest that the Sr+HF reaction often proceeds via multiple encounters which scramble the reagent energy modes during the course of a reactive collision.