MoRu(CO)6(bis(diphenylphosphino)methane)2 | 133017-73-9

• 英文名称: MoRu(CO)6(bis(diphenylphosphino)methane)2
• 英文别名: [MoRu(CO)6(μ-bis(diphenylphosphino)methane)2]；(CO)3Mo(μ-dppm)2Ru(CO)3
• CAS: 133017-73-9
• 化学式: C₅₆H₄₄MoO₆P₄Ru
• 分子量: 1133.87
• InChiKey: KEZGSZYCDRRGFT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  MoRu(CO)6(bis(diphenylphosphino)methane)2 以 甲苯 为溶剂， 生成 pentacarbonyl bis(bisdiphenylphosphinomethane)molybdenum ruthenium (Mo=Ru)
  参考文献：
  名称：

  Chaudret, Bruno; Dahan, Françoise; Sabo, Sylviane, Organometallics, 1985, vol. 4, # 8, p. 1490 - 1492

  摘要：

  DOI：

文献信息

• Reaction of H₂S with MoRu(CO)₆(dppm)₂ to give H₂ and a bridged-sulfide product via hydrido-sulfhydryl intermediates (dppm = Ph₂PCH₂PPh₂)
  作者：Mozhgan Khorasani-Motlagh、Nasser Safari、Craig B Pamplin、Brian O Patrick、Brian R James

  DOI：10.1139/v06-002

  日期：2006.2.1

  is also formed directly from the reaction of 1 with elemental sulfur. The solid-state molecular structure of 5 is determined by X-ray crystallography. A further hydrido-sulfhydryl species, possibly Mo(CO)3(µ-SH)(µ-H)(µ-dppm)2Ru(CO)2 (3), is in equilibrium with 2 at ambient temperature.Key words: molybdenum, ruthenium, bis(diphenylphosphino)methane, hydrogen sulfide, hydrido-sulfhydryl species, carbonyl

  在约 20 °C 的甲苯中将 H2S 氧化添加到 MoRu(CO)6(µ-dppm)2 (1) 中，生成可分离的复合物，配制成 Mo(CO)3(µ-SH)(µ-CO)(µ- dppm)2RuH(CO) (2) 通过可能的中间体 Mo(CO)3(µ-H)(µ-CO)(µ-dppm)2Ru(SH)(CO) (4) (dppm = Ph2PCH2PPh2) 即在较低温度下可检测到。2 天后，甲苯中的物质 2 失去 H2（和 CO），生成桥接硫化物产物 Mo(CO)2(µ-CO)(µ-S)(µ-dppm)2Ru(CO) (5)也直接由 1 与元素硫反应形成。5 的固态分子结构由 X 射线晶体学确定。另一种氢化巯基物质，可能是 Mo(CO)3(µ-SH)(µ-H)(µ-dppm)2Ru(CO)2 (3)，在环境温度下与 2 处于平衡状态。 关键词：钼, 钌, 双(二苯基膦)甲烷, 硫化氢, 氢化-巯基物质
• Oxidative addition of halogens to MoRu(CO)6(dppm)2
  作者：Mozhgan Khorasani-Motlagh、Nasser Safari、Craig B Pamplin、Brian O Patrick、Brian R James

  DOI：10.1016/s1387-7003(03)00217-x

  日期：2003.9

  Halogens oxidatively add to MoRu(CO)(6)(mu-dppm)(2) (1) at ambient temperature to yield [(CO)(2)Mo(mu-X)(mu-CO)(mu-dpmm)(2)Ru(CO)(2)] (divided by)[Mo(CO)(4) X-3](-), where X = Cl (2) or I (3), dppm - Ph2PCH2PPh2, and the mu-CO is semi-bridging. Complexes 2 and 3 have been characterized by elemental analysis, conductivity, and NMR spectroscopy, while the molecular structure of 3 has been determined by X-ray crystallography. Ignoring a weak metal-metal bond interaction, the cation of 3 is most easily described as pseudo-octahedral at Ru(II) and Mo(0) centres; the anion is a monocapped octahedron that has been described previously. (C) 2003 Elsevier B.V. All rights reserved.
• Laarab, H. Ben; Chaudret, B.; Dahan, F., New Journal of Chemistry, 1990, vol. 14, p. 321 - 330
  作者：Laarab, H. Ben、Chaudret, B.、Dahan, F.、Devillers, J.、Poilblanc, R.、Sabo-Etienne, S.

  DOI：——

  日期：——
• Oxidative addition of thiols to (CO)3Mo(μ-dppm)2Ru(CO)3 with formation of hydrido, bridged-thiolate complexes (dppm=Ph2PCH2PPh2)
  作者：Mozhgan Khorasani-Motlagh、Nasser Safari、Craig B. Pamplin、Brian O. Patrick、Brian R. James

  DOI：10.1016/j.ica.2009.12.002

  日期：2010.3

  The room temperature reactions of RSH (R = Et, Ph) with (CO)(3)Mo(mu-dppm)(2)Ru(CO)(3) (1) in toluene yield (CO)(2)Mo(mu-SR)(mu-CO)(mu-dppm)(2)Ru(H)(CO) [R = Et (3); Ph (4)], which are characterized by elemental analysis, H-1 NMR and IR spectroscopies and, in the case of 3, by X-ray crystallography. The complexes contain a trans, trans-Mo(mu-dppm)(2)Ru unit with a bridging thiolate, a terminal hydride at the Ru, three terminal CO ligands (two at the Mo, and one at the Ru), and one semi-bridged CO closer to the Mo. (C) 2009 Elsevier B. V. All rights reserved.