dimethyl-(4-trifluoromethyl-6-methylpyrimidine-2-thionate)thallium(III) | 620622-80-2

• 英文名称: dimethyl-(4-trifluoromethyl-6-methylpyrimidine-2-thionate)thallium(III)
• CAS: 620622-80-2
• 化学式: C₃₂H₄₀F₁₂N₈S₄Tl₄
• 分子量: 1710.5
• InChiKey: IBTWRSUDBQOXRN-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dimethylthallium,hydrate 、 6-methyl-4-(trifluoromethyl)pyrimidine-2-thione 以 甲醇 、 水 为溶剂， 以47%的产率得到dimethyl-(4-trifluoromethyl-6-methylpyrimidine-2-thionate)thallium(III)
  参考文献：
  名称：

  A novel ligational mode of pyrimidine-2-thione. Molecular structure of dimethyl-(4-trifluromethyl-6-methylpyrimidine-2-thionate)thallium(III)

  摘要：

  The reaction between 4-trifluromethyl-6-methylpyrimidine-2-thione (4-CF3-6-CH(3)pymSH) and dimethylthallium(III) hydroxide in methanol yielded [Me2Tl(4-CF3-6-CH(3)pymS)](4); this compound exhibits a tetranuclear structure with thionate ligands acting as bridges between two metallic atoms. Vibrational and H-1, C-13 and Tl-205 NMR spectra of the complex are discussed and related to the structure. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1387-7003(03)00054-6