| 76332-01-9

• CAS: 76332-01-9
• 化学式: C₅ClO₉Re
• 分子量: 425.71
• InChiKey: XSGANOHQBPIASF-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 乙腈 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Technetium and rhenium pentacarbonyl perchlorates: Structure and reactivity

  摘要：

  Carbonyl perchlorates [M(ClO4)(CO)(5)] (M = Tc, Re) were prepared by treatment of [TcI(CO)(5)] and [ReCl(CO)(5)], respectively, with AgClO4 in dichloromethane. The complexes were isolated in the form of yellowish and colorless crystals, respectively, and characterized by IR spectroscopy and single crystal X-ray diffraction (XRD). Perchlorate ion is coordinated to the central atom in the monodentate fashion. Perchlorate ligand in the coordination sphere of [M(ClO4)(CO)(5)] (M = Tc, Re) can be readily substituted by a molecule of a coordinating solvent (acetonitrile). [Re(CO)(5)(CH3CN)]ClO4 is stable with respect to thermal decarbonylation and was isolated and characterized by single crystal XRD. The coordination polyhedron of rhenium in [Re(CO)(5)(CH3CN)]ClO4 is less distorted than that in [M(ClO4)(CO)(5)]. [Tc(CO)(5)(CH3CN)]ClO4, contrary to its rhenium analog, is unstable in acetonitrile solution and undergoes rapid decarbonylation to form [Tc(CO)(3)(CH3CN)(3)]ClO4. (C) 2013 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2013.07.019
• 作为产物：
  描述：

  五羰基氯铼(I) 、 silver perchlorate 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  具有 N,N'-双齿配体和异氰基乙酸乙酯的 2+1 三羰基铼配合物：合成、结构和性质

  摘要：

  摘要 2+1 三羰基配合物 [Re(CO) 3 (N^N)CNCH 2 COOEt ]X，其中 N^N = 2,2'-联吡啶 (bipy) 或 1,10-菲咯啉 (phen) 且 X = Cl –或 ClO 4 –，通过两个程序制备和分离。中间体三羰基配合物 [Re(CO) 3 (N^N)X]（其中 X = Cl –或 ClO 4 –）也被分离出来。这些配合物的组成和分子结构通过单晶X射线衍射分析确定。该配合物具有fac-三羰基结构，具有bipy和phen的双齿配位。通过 PL、IR、UV-Vis 和1对配合物进行了表征H NMR光谱和元素分析。

  DOI：

  10.1134/s1070363222010108

文献信息

• [Re(CO)3(bipy)(ClO4)]: Synthesis in a Proton-Donor Solvent, Crystal, and Molecular Structure
  作者：A. E. Miroslavov、G. V. Sidorenko、M. Yu. Tyupina、V. V. Gurzhiy

  DOI：10.1134/s1070363220120178

  日期：2020.12

  The complex [Re(CO)3(bipy)(ClO4)] (bipy = 2,2ʹ-bipyridine) was prepared by the reaction of [Re(CO)3(H2O,EtOH)3](ClO4) with bipy in aqueous ethanol, followed by crystallization from dichloromethane. The composition and structure of the complex were determined by single crystal X-ray diffraction analysis. The complex has a molecular octahedral structure with bidentate coordination of bipy and inner-sphere

  [Re(CO)3(bipy)(ClO4)] (bipy = 2,2ʹ-联吡啶) 由 [Re(CO)3(H2O,EtOH)3]( ) 与 bipy 在水溶液中反应制备乙醇，然后从二氯甲烷中结晶。配合物的组成和结构通过单晶X射线衍射分析确定。该配合物具有分子八面体结构，在与bipy的面位上具有bipy的双齿配位和高氯酸根离子的内球单齿配位。该复合物还通过红外和紫外-可见吸收光谱进行了表征。
• Technetium and Rhenium Pentacarbonyl Complexes with C₂ and C₁₁ ω-Isocyanocarboxylic Acid Esters
  作者：Alexander E. Miroslavov、Yuriy S. Polotskii、Vladislav V. Gurzhiy、Alexander Yu. Ivanov、Alexander A. Lumpov、Margarita Yu. Tyupina、Georgy V. Sidorenko、Peter M. Tolstoy、Daniil A. Maltsev、Dmitry N. Suglobov

  DOI：10.1021/ic500327s

  日期：2014.8.4

  Technetium(I) and rhenium(I) pentacarbonyl complexes with ethyl 2-isocyanoacetate and methyl 11-isocyanoundecanoate, [M(CO)5(CNCH2COOEt)]ClO4 (M = Tc (1) and Re (2)) and [M(CO)5(CN(CH2)10COOMe)]ClO4 (M = Tc (3) and Re (4)), were prepared and characterized by IR, 1H NMR, and 13C1H} NMR spectroscopy. The crystal structures of 1 and 2 were determined using single-crystal X-ray diffraction. The kinetics

  carbonyl（I）和rh（I）五羰基配合物与2-异氰基乙酸乙酯和11-异氰基十一酸甲酯，[M（CO）5（CNCH 2 COOEt ）] ClO 4（M = Tc（1）和Re（2））和制备了[M（CO）5（CN（CH 2）10 COOMe）] ClO 4（M = Tc（3）和Re（4）），并通过IR，1 H NMR和13 C 1 H}进行了表征。NMR光谱。1和2的晶体结构用单晶X射线衍射测定。通过红外光谱研究了complex络合物1和3在乙二醇中的热脱羰反应动力学。确定该反应的速率常数和活化参数，并与[Tc（CO）6 ] +的常数和比较。发现rh配合物2和4对于热脱羰作用是稳定的。组氨酸1和2的组氨酸激发反应通过红外光谱检查磷酸盐缓冲液中的H 2 O 3。在组氨酸存在下，pen羰基五羰基异氰化物配合物会部分分解，形成黄色沉淀物。net类似物1在这些条件下更稳定。
• “2+1B” Tricarbonyl Complexes of Technetium-99m and Rhenium with N,N '-Bidentate Ligands and Methyl 2-(Decylthio)-6-isocyanohexanoate
  作者：A. E. Miroslavov、V. V. Kuz’min、A. P. Sakhonenkova、M. Yu. Tyupina、G. V. Sidorenko、A. R. Kochergina、V. A. Polukeev

  DOI：10.1134/s1066362223060085

  日期：2023.12

  Abstract “2+1B” tricarbonyl complexes of the general formula [M(CO)3(N^N)CN(CH2)4CH(COOMe)SC10H21]-ClO4, where M = 99mTc or Re, N^N = 2,2'-bipyridine (bipy) or 1,10-phenanthroline (phen), were prepared by the reaction of [M(CO)3(N^N)(MeOH)]ClO4 with methyl 2-(decylthio)-6-isocyanohexanoate in methanol. The rhenium complexes were isolated and characterized by 1H NMR and IR spectroscopy. The formation

  摘要 “2+1 B ”三羰基络合物，通式为 [M(CO) 3 (N^N)CN(CH 2 ) 4 CH(COOMe)SC 10 H 21 ]-ClO 4，其中 M = 99 m Tc 或 Re , N^N = 2,2'-联吡啶 (bipy) 或 1,10-菲咯啉 (phen)，由 [M(CO) 3 (N^N)(MeOH)]ClO 4与甲基 2反应制备-(癸硫基)-6-异氰基己酸酯的甲醇溶液。铼络合物被分离并通过1 H NMR 和 IR 光谱进行表征。通过HPLC证实了锝-99 m复合物的形成。测量了锝络合物的亲脂性。
• Photochemistry of metal-metal bonded complexes: one-electron oxidation of photogenerated seventeen-valence-electron radicals
  作者：Aloysius F. Hepp、Mark S. Wrighton

  DOI：10.1021/ja00395a064

  日期：1981.3
• Horn, Ernst; Snow, Michael, R., Australian Journal of Chemistry, 1980, vol. 33, # 11, p. 2369 - 2376
  作者：Horn, Ernst、Snow, Michael, R.

  DOI：——

  日期：——