[(1-pyridyl-(3-t-butylimidazole-2-thione)NiBr2] | 1103641-02-6

• 英文名称: [(1-pyridyl-(3-t-butylimidazole-2-thione)NiBr2]
• CAS: 1103641-02-6
• 化学式: C₁₂H₁₅Br₂N₃NiS
• 分子量: 451.835
• InChiKey: NOLCFTMJILYSFD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  乙二醇二甲醚溴化镍 、 1-pyridyl-(3-t-butylimidazole-2-thione) 以 二氯甲烷 为溶剂， 以78%的产率得到[(1-pyridyl-(3-t-butylimidazole-2-thione)NiBr2]
  参考文献：
  名称：

  Synthesis, characterization and olefin polymerization of the nickel catalysts supported by [N,S] ligands

  摘要：

  The novel nickel (II) complexes (2a, 2b) bearing 1-pyridyl-(3-substituedimidazole-2-thione) ligands were synthesized by the reaction of the corresponding ligands with NiBr2(DME). 2a and 2b have been characterized by IR, NMR and elemental analysis. The nickel complexes show high catalytic activities for norbornene polymerization in the presence of MAO (methylaluminoxane), although low activities for ethylene polymerization. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.10.009