| 915712-74-2

• CAS: 915712-74-2
• 化学式: AlCl₄*C₁₈H₂₆Al
• 分子量: 438.18
• InChiKey: XQKXVFQLYGQEQI-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三氯化铝 、 tris(tetramethylcyclopentadienyl)aluminium 以 further solvent(s) 为溶剂， 以56%的产率得到
  参考文献：
  名称：

  Synthesis and Characterization of [(C₅Me₄H)₂Al]⁺, an Initiator for the Polymerization of Isobutene. X-ray Crystal Structures of [(C₅Me₄H)₂Al(μ-Cl)]₂ and [(C₅Me₄H)₂Al][B(C₆F₅)₄]

  摘要：

  The octamethylaluminocenium cation [ Cp'Al-2](+) ( Cp') C5Me4H) was formed both by halide abstraction in the reaction between [ Cp'2AlCl](2) and AlCl3 and by cyclopentadienide abstraction in the reaction between Cp'Al-3 and [ CPh3][ B( C6F5)](4). [ Cp'Al-2](+) is less thermally stable than [ Cp*Al-2]+ ( Cp*) C5Me5) but is more active as an initiator for isobutene polymerization. The X-ray crystal structures of [ Cp'2AlCl](2) and [ Cp'Al-2][ B( C6F5)(4)] are reported.

  DOI：

  10.1021/om0606439