[N(PPh3)2][1,2-closo-C2B10I10H] | 887478-11-7

• 英文名称: [N(PPh3)2][1,2-closo-C2B10I10H]
• CAS: 887478-11-7
• 化学式: C₂HB₁₀I₁₀*C₃₆H₃₀NP₂
• 分子量: 1940.77
• InChiKey: OSPMJTKWESXEQW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,2-closo-C₂B₁₀I₁₀H^(1-) 、 双(三苯基正膦基)氯化铵 以 水 为溶剂， 生成 [N(PPh3)2][1,2-closo-C2B10I10H]
  参考文献：
  名称：

  Synthesis of Boron-Iodinated o-Carborane Derivatives. Water Stability of the Periodinated Monoprotic Salt

  摘要：

  Boron periodination of o-carborane has been achieved by taking account of the fact that B atoms in the cluster are of two types, i.e., those adjacent to both C atoms and the remainder. The high number of nonequivalent leaving groups opens the possibility through B-C coupling to materials with novel possibilities and to self-assembling due to the enhanced polarizability of the C-H bond. Periodination has accentuated the acidity of the carborane, and monoprotic salts are stable in water.

  DOI：

  10.1021/ic060124y