Co(5-chloro-2-aminepyridypropionamide)2Cl2 | 679786-68-6

• 英文名称: Co(5-chloro-2-aminepyridypropionamide)2Cl2
• CAS: 679786-68-6
• 化学式: C₁₆H₁₈Cl₄CoN₄O₂
• 分子量: 499.15
• InChiKey: XPLABHAYUREGPB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Co(5-chloro-2-aminepyridypropionamide)2Cl2 以 neat (no solvent) 为溶剂， 生成 钴 、 cobalt(II) chloride
  参考文献：
  名称：

  Synthesis, characterization and thermal behavior of cobalt(II) 5-chloro-piridylamides complexes

  摘要：

  Purple cobalt(II) complexes containing 5-chloro-2-aminepyridylacetamide (CPA), 5-chloro-2-aminepyridylpropionamide (CPP) and 5-chloro-2-aminepyridylbutyramide (CPB) ligands were prepared from ethanolic solutions. The general stoichiometry CoL2Cl2 (L = ligand) was determined from elemental analysis data. Infrared results show monodentate CPA and CPP ligands through the aromatic nitrogen atom, CPB is bidentate through the aromatic nitrogen atom and carboxyl group. Thermogravimetric curves under nitrogen showed in the final stage all complexes presented a mixture of cobalt(II) chloride and metallic cobalt as residue. The complexes containing CPA and CPP ligands decomposed in various stages with integral loss of ligand or partial loss of the chloride. Only two steps of decomposition are seen for CPB compound. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0040-6031(03)00285-5
• 作为产物：
  描述：

  2-(N-Propionylamino)-5-chlor-pyridin 、 cobalt(II) chloride 以 乙醇 为溶剂， 生成 Co(5-chloro-2-aminepyridypropionamide)2Cl2
  参考文献：
  名称：

  Synthesis, characterization and thermal behavior of cobalt(II) 5-chloro-piridylamides complexes

  摘要：

  Purple cobalt(II) complexes containing 5-chloro-2-aminepyridylacetamide (CPA), 5-chloro-2-aminepyridylpropionamide (CPP) and 5-chloro-2-aminepyridylbutyramide (CPB) ligands were prepared from ethanolic solutions. The general stoichiometry CoL2Cl2 (L = ligand) was determined from elemental analysis data. Infrared results show monodentate CPA and CPP ligands through the aromatic nitrogen atom, CPB is bidentate through the aromatic nitrogen atom and carboxyl group. Thermogravimetric curves under nitrogen showed in the final stage all complexes presented a mixture of cobalt(II) chloride and metallic cobalt as residue. The complexes containing CPA and CPP ligands decomposed in various stages with integral loss of ligand or partial loss of the chloride. Only two steps of decomposition are seen for CPB compound. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0040-6031(03)00285-5