[Pd(C6H2(CH2SPh)-2,6-(OH)-4)(MeCN)]BF4 | 1070260-80-8

• 英文名称: [Pd(C6H2(CH2SPh)-2,6-(OH)-4)(MeCN)]BF4
• CAS: 1070260-80-8
• 化学式: BF₄*C₂₂H₂₀NOPdS₂
• 分子量: 571.764
• InChiKey: NMVPARIAFNHPHC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Pd(C6H2(CH2SPh)-2,6-(OH)-4)(MeCN)]BF4 在 triethylamine 、 4-(dimethylamino)pyridine 作用下， 以 二氯甲烷 、 水 、 乙腈 为溶剂， 生成 [PdBr(C6H2(CH2SPh)2-2,6-((EtO)3Si(CH2)3NHCO2-4)]
  参考文献：
  名称：

  Self-assembly of para-OH functionalized ECE-metalated pincer complexes

  摘要：

  Various para-OH functionalized ECE-pincer metal complexes [MX(ECE-OH)L-n] (ECE-OH = [C6H2(CH2E)(2)-2,6- OH-4] , E = NMe2, PPh2 and SPh) were synthesized. The X-ray crystal structures of neutral [PdCl(SCS-OH)], [PdCl(NCN-OH)], and cationic [Pd(PCP-OH)(MeCN)](BF4) are reported. The neutral halide complexes exhibit self-assembly to form polymeric chains via H-bonding involving the para-OH group as donors and the halide ligand on the metal as acceptors. Moreover, the halide ligand can be replaced by a monomeric aryloxy-O ligand leading to the formation of a covalently bonded dimer. The crystal structure of such a dimer derived from [PdI(NCN-OH)] is reported. Furthermore, these pincer-metal complexes were tethered through a carbamate linker to a siloxane functionality with the aim to be immobilized on a silica support. The crystal structure of a siloxane-functionalized [PtI(NCN-Z)] complex exemplifies how other H-bonding interactions not involving the metal-halide groupings can lead to polymeric networks as well. (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.06.016
• 作为产物：
  描述：

  双(乙腈)氯化钯(II) 、 (3,5-Bis-phenylsulfanylmethyl-phenoxy)-tert-butyl-dimethyl-silane 、 silver tetrafluoroborate 以 乙腈 为溶剂， 以84%的产率得到[Pd(C6H2(CH2SPh)-2,6-(OH)-4)(MeCN)]BF4
  参考文献：
  名称：

  Self-assembly of para-OH functionalized ECE-metalated pincer complexes

  摘要：

  Various para-OH functionalized ECE-pincer metal complexes [MX(ECE-OH)L-n] (ECE-OH = [C6H2(CH2E)(2)-2,6- OH-4] , E = NMe2, PPh2 and SPh) were synthesized. The X-ray crystal structures of neutral [PdCl(SCS-OH)], [PdCl(NCN-OH)], and cationic [Pd(PCP-OH)(MeCN)](BF4) are reported. The neutral halide complexes exhibit self-assembly to form polymeric chains via H-bonding involving the para-OH group as donors and the halide ligand on the metal as acceptors. Moreover, the halide ligand can be replaced by a monomeric aryloxy-O ligand leading to the formation of a covalently bonded dimer. The crystal structure of such a dimer derived from [PdI(NCN-OH)] is reported. Furthermore, these pincer-metal complexes were tethered through a carbamate linker to a siloxane functionality with the aim to be immobilized on a silica support. The crystal structure of a siloxane-functionalized [PtI(NCN-Z)] complex exemplifies how other H-bonding interactions not involving the metal-halide groupings can lead to polymeric networks as well. (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.06.016