[Ru(η5-C5H5)(DPPE)2(1-methylimidazole)][BPh4] | 1384458-28-9

• 英文名称: [Ru(η5-C5H5)(DPPE)2(1-methylimidazole)][BPh4]
• CAS: 1384458-28-9
• 化学式: C₂₄H₂₀B*C₃₈H₄₁N₂P₂Ru
• 分子量: 1008.01
• InChiKey: DHUYKUGOJLKAIQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N-丁基咪唑 、 chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II) 、 四苯基硼酸铵 以 甲醇 为溶剂， 以81%的产率得到[Ru(η5-C5H5)(DPPE)2(1-methylimidazole)][BPh4]
  参考文献：
  名称：

  Synthesis and structural characterization of new piano-stool ruthenium(II) complexes bearing 1-butylimidazole heteroaromatic ligand

  摘要：

  New cationic ruthenium(II) complexes with the formula [Ru(eta(5)-C5H5)(LL)(1-BuIm)] [Z], with (LL) = 2PPh(3) or DPPE, and Z = CF3SO3-, PF6-, BPh4-, have been synthesized and fully characterized. Spectroscopic and electrochemical studies revealed that the electronic properties of the coordinated 1-butylimidazole were clearly influenced by the nature of the phosphane coligands (LL) and also by the different counter ions. The solid state structures of the six complexes determined by X-ray crystallographic studies, confirmed the expected distorted three-legged piano stool structure. However the geometry of the 1-butylimidazole ligand was found considerably different in all six compounds, being governed by the stereochemistry of the mono and bidentate coligands (PPh3 or DPPE). (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.04.024