| 823235-04-7

• CAS: 823235-04-7
• 化学式: C₅₆H₉₂N₄O₁₀S₈Sn₄
• 分子量: 1712.74
• InChiKey: QGODSQVPEQQIOC-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二正丁基氧化锡 、 2-巯基-4-甲基-5-噻唑乙酸 在 air 作用下， 以 苯 为溶剂， 以65%的产率得到
  参考文献：
  名称：

  Synthesis and crystal structure of macrocyclic di-n-butyltin(IV) complex with 2-mercapto-4-methyl-5-thiazoleacetic acid, {[n-Bu2Sn(O2CCH2C4H3NS)SS(C4H3NSCH2CO2)Sn n-Bu2]O}2

  摘要：

  A novel macrocyclic di-n-butyltin(IV) complex 1 was synthesized by the reaction of di-n-butyltin(IV) oxide and 2-mercapto-4-methyl-5-thiazoleacetic acid. Characterization of the complex 1 was achieved using elemental analysis, IR, H-1, C-13 and Sn-119 NMR spectra and X-ray diffraction. X-ray data of the complex 1 revealed that it is an unusual macrocycle containing the bridging-S-S-linkages and tetranuclear ladder based on a planar four-membered Sn2O2 ring. In the so-called ladder structure, there are two distinct tin environments, the endocyclic tin atom is best described as five-coordinate and the exocyclic tin atom as six-coordinate. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.06.026