1-dibutylboryl-2-diphenylphosphino-1-butyl-2-phenylethene oxide | 127114-64-1

• 英文名称: 1-dibutylboryl-2-diphenylphosphino-1-butyl-2-phenylethene oxide
• CAS: 127114-64-1
• 化学式: C₃₂H₄₂BOP
• 分子量: 484.47
• InChiKey: JYGMPCFBSDOXML-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1-dibutylboryl-2-diphenylphosphino-1-butyl-2-phenylethene selenide 以 乙腈 为溶剂， 以74%的产率得到selenium
  参考文献：
  名称：

  Products of the electrochemical reduction of borylphosphinoethene in a nonaqueous medium

  摘要：

  In order to confirm our earlier assumptions with respect to the processes involved in the electrochemical reduction of borylphosphinoethene derivatives, we have analyzed the products of controlled-potential electrolysis. Compounds were isolated and identified, formed in the further chemical conversions of the initially formed unstable intermediates. It has been demonstrated that the electroreduction of the borylphosphinoethene oxide in an aprotic medium leads primarily to splitting of the P-C(Ar) bond and in the case of the borylphosphinoethene selenide to the reduction of the P = Se bond; in the reduction of the corresponding sulfide both these fragments are affected.

  DOI：

  10.1007/bf00959651