[(n-Bu2Sn)4(12-(4-methylbenzoyl)-9,10-dihydro-9,10-ethanoanthracene-11-carboxylate)2O2(OC2H5)2] | 1187847-40-0

• 英文名称: [(n-Bu2Sn)4(12-(4-methylbenzoyl)-9,10-dihydro-9,10-ethanoanthracene-11-carboxylate)2O2(OC2H5)2]
• CAS: 1187847-40-0
• 化学式: C₈₆H₁₂₀O₁₀Sn₄
• 分子量: 1788.73
• InChiKey: LWQACHFEEKCXKU-OUTJTCTNSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  12-(4-methylbenzoyl)-9,10-dihydro-9,10-ethanoanthracene-11-carboxylic acid 、 二正丁基氧化锡 以 苯 为溶剂， 以58.6%的产率得到[(n-Bu2Sn)4(12-(4-methylbenzoyl)-9,10-dihydro-9,10-ethanoanthracene-11-carboxylate)2O2(OC2H5)2]
  参考文献：
  名称：

  Synthesis, crystal structure and biological activities of two novel organotin(IV) complexes constructed from 12-(4-methylbenzoyl)-9,10-dihydro-9,l0-ethanoanthracene-11-carboxylic acid

  摘要：

  Two complexes: [(n-Bu2Sn)(4)(L)(2)O-2(OC2H5)(2)] (1) and [(C6H5)(3)Sn(L)] (2) (where, HL is 12-(4-methylbenzoyl)- 9,10-dihydro-9,10-ethanoanthracene-11-carboxylic acid) have been prepared and structurally characterized by means of elemental analysis and vibrational, 1H NMR and FT-IR spectroscopies. The crystal structures of 1 and 2 have been determined by X-ray crystallography. Three distannoxane rings are present to the centrosymmetric dimeric tetraorganodistannoxane by virtue of 13-oxo form the central R4Sn2O2 core with a planar Sn2O2 ring, resulting in a ladder type structural motif in the molecular structure of 1, and five-coordinated tin atoms are present in the distannoxane dimer. While the molecular of 2 adopts a monomeric distorted tetrahedral configuration with the carboxylate ligand coordinating in a monodentate mode. Both 1 and 2 exhibited good antibacterial and antitumour activities and have a potential to be used as drugs. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.04.040