tris(N,N-dimethyldithiocarbamato)iron(IV) tetrachloroferrate(III) | 121856-29-9

• 英文名称: tris(N,N-dimethyldithiocarbamato)iron(IV) tetrachloroferrate(III)
• CAS: 121856-29-9
• 化学式: C₉H₁₈FeN₃S₆*Cl₄Fe
• 分子量: 614.164
• InChiKey: PQGNCGFTZCLXAM-UHFFFAOYSA-G

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  tris(N,N-dimethyldithiocarbamato)iron(IV) tetrachloroferrate(III) 以 乙醇 为溶剂， 生成 chlorobis(N,N-dimethyldithiocarbamato)iron(III)
  参考文献：
  名称：

  Oxidation of tetramethylthiuram sulfide and iron(III) dithiocarbamates with ferric chloride

  摘要：

  The title systems lead to the haloferrate(III) salt of the large 3,5-bis(N,N-dimethyliminium)-1,2,4-trithiolane cation. Oxidation of the iron(III) dithiocarbamates occurs stepwise through the formation of several intermediates, which are isolated and characterized. An alternative route to the oxidation of the thiuram sulfide is presented. All compounds were characterized by analyses, IR and UV spectroscopy, as well as magnetic measurements.

  DOI：

  10.1016/0277-5387(95)00380-0
• 作为产物：
  描述：

  ferbam 以 二氯甲烷 为溶剂， 生成 tris(N,N-dimethyldithiocarbamato)iron(IV) tetrachloroferrate(III)
  参考文献：
  名称：

  Oxidation of tetramethylthiuram sulfide and iron(III) dithiocarbamates with ferric chloride

  摘要：

  The title systems lead to the haloferrate(III) salt of the large 3,5-bis(N,N-dimethyliminium)-1,2,4-trithiolane cation. Oxidation of the iron(III) dithiocarbamates occurs stepwise through the formation of several intermediates, which are isolated and characterized. An alternative route to the oxidation of the thiuram sulfide is presented. All compounds were characterized by analyses, IR and UV spectroscopy, as well as magnetic measurements.

  DOI：

  10.1016/0277-5387(95)00380-0