[(Sn(n-Bu)2)4(4-triazolylbenzoate)2O2(MeO)2] | 1353548-26-1

• 英文名称: [(Sn(n-Bu)2)4(4-triazolylbenzoate)2O2(MeO)2]
• CAS: 1353548-26-1
• 化学式: C₅₂H₉₀N₆O₈Sn₄
• 分子量: 1402.16
• InChiKey: SMFJQUGCMMEAPM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  甲醇 、 4-(1,2,4-三唑-1-基)苯甲酸 、 氧气 、 二正丁基氧化锡 以 甲苯 为溶剂， 以37%的产率得到[(Sn(n-Bu)2)4(4-triazolylbenzoate)2O2(MeO)2]
  参考文献：
  名称：

  Synthesis and structural characterization of organotin(IV) carboxylates based on different heterocyclic substituents

  摘要：

  Six novel organotin(IV) carboxylates have been successfully synthesized, namely, the polymer (C6H5)(3)Sn(L1)(infinity) (1) [HL1 = 4-imidazolyl benzoic acid], the mononuclear (C6H5)(3)Sn(L2) (2) [HL2 = 4-pyrazolylbenzoic acid], (C6H5)(3)Sn(L3)center dot CH3OH (3) [HL3 = 4-triazolylbenzoic acid] and (C6H5)(3)Sn(L4) (4) [HL4 = 4-tetrazolyl benzoic acid] and the tetranuclear [(n-Bu2Sn)(4)(L2)(2)O-2(OCH3)(2)] (5) and [(n-Bu2Sn)(4)(L3)(2)O-2(OCH3)(2)] (6). X-ray diffraction analyses show 1D infinite chain of polymer 1, single molecular structures of isomorphous complexes 2 and 4, single molecule structures of complex 3 containing solvent CH3OH molecule and similar ladder-type structures of complexes 5 and 6. The photoluminescence of ligands and 1-6 were also measured in the solid state at room temperature. (C) 2011 Published by Elsevier Ltd.

  DOI：

  10.1016/j.poly.2011.10.032