[Cu4(μ4-O)(μ-H2bpmp)2(μ1,3-O2CCH2Ph)4] | 1428987-74-9

• 英文名称: [Cu4(μ4-O)(μ-H2bpmp)2(μ1,3-O2CCH2Ph)4]
• 英文别名: [Cu₄(μ₄-O)(μ-2,6-bis[(3-hydroxypropylimino)methyl]-4-methylphenol)₂(μ_1,3-phenylacetate)₄]；[Cu₄(μ₄-O)(μ-H₂bpmp)₂(μ_1,3-O₂CCH₂Ph)₄]
• CAS: 1428987-74-9
• 化学式: C₆₂H₇₀Cu₄N₄O₁₅
• 分子量: 1365.44
• InChiKey: INDFIYDHUQNQTP-UVGXFSDVSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  copper (II) phenylacetate monohydrate 、 2,6-bis-[(3-hydroxy-propylimino)-methyl]-4-methyl-phenol 在 三乙胺 作用下， 以 甲醇 为溶剂， 反应 2.0h， 以78%的产率得到[Cu4(μ4-O)(μ-H2bpmp)2(μ1,3-O2CCH2Ph)4]
  参考文献：
  名称：

  New μ-hydroxido-bridged copper nitrate dimer and μ4-oxido-bridged copper phenylacetate quasi-tetrahedron: Direct synthesis and uphill conversion

  摘要：

  Dinuclear [Cu-2(mu-OH)] fragment and its self-assembled tetranuclear part [Cu-2(mu(4)-O)Cu-2] are found in two copper(II) complexes of ligand H3bpmp: [Cu-2(mu(2)-OH)(mu-H(2)bpmp)(mu(1.3)-NO3)][Cu-2(mu(2)-OH)(mu-H(2)bpmp)(NO3)(H2O)](NO3)2 center dot 2H(2)O (1 center dot 2H(2)O) and [Cu-4(mu(2)-OH)(mu-H(2)bpmp)(2)(mu(1.3)-O2CCH2Ph)(4)] (2) [H(3)bpmp = 2,6-bis-[(3-hydroxy-propylimino)-methyl]-4-methylphenoll. These complexes have been synthesized and characterized by single crystal X-ray crystallography. Complex 1 showed unique reactivity with phenylacetate anions to provide 2 in which two [Cu-2(mu(2)-OH)] units available within same crystal lattice collapsed to give [Cu-4(mu(4)-O)] hub. Formation of the [Cu-4] compound is also achieved from individual components and phenylacetate ligands, which allows an effective tuning of the self-assembly of two ligand bound [Cu-2] fragments and removal of H+ from hydroxido bridges to provide oxido nucleus. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.08.064