[Ti(2,2'-bipyridyl)3]BF4 | 679398-41-5

• 英文名称: [Ti(2,2'-bipyridyl)3]BF4
• CAS: 679398-41-5
• 化学式: BF₄*C₃₀H₂₄N₆Ti
• 分子量: 603.245
• InChiKey: VYTJPLJJEMHZHO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tris-bipyridyl-(2,2') titanium (0) 、 三氟化硼 以 二氯甲烷 为溶剂， 以43%的产率得到[Ti(2,2'-bipyridyl)3]BF4
  参考文献：
  名称：

  Reactivity of Ti(bipy)3 and preparation of the Li(THF)4[Al(bipy)2] complex with the dinegative bipy ligand

  摘要：

  The reaction of Ti(bipy)(3) with BF3 resulted in the formation of [Ti(bipy)(3)]BF4 (1), whereas the interaction of Ti(bipy)(3) with the LiAlH4 yielded the unforeseen aluminum complex Li(THF)(4)[Al(bipy)(2)] (2). The complexes 1 and 2 were characterized by NMR, mass spectra and elemental analysis. Complex 2 was investigated by X-ray structural analysis and consists of cationic [Li(THF)(4)](+) and anionic [Al(bipy)(2)](-) units containing the coordinated dinegatively charged [bipy] ligand. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2003.10.008