(pentakis(acetoxymercurio)cyclopentadienyl)rhenium tricarbonyl | 155642-22-1

• 英文名称: (pentakis(acetoxymercurio)cyclopentadienyl)rhenium tricarbonyl
• CAS: 155642-22-1
• 化学式: C₁₈H₁₅Hg₅O₁₃Re
• 分子量: 1628.47
• InChiKey: YCUJADGKFZFLHZ-UHFFFAOYSA-I

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  环戊二烯三羰基铼 、 mercury(II) diacetate 以 二氯甲烷 为溶剂， 以90%的产率得到(pentakis(acetoxymercurio)cyclopentadienyl)rhenium tricarbonyl
  参考文献：
  名称：

  环戊二烯基锰三羰基和环戊二烯基r三羰基的五聚。（五碳环戊二烯基）三羰基锰的晶体结构

  摘要：

  Treatment of cyclopentadienylmanganese tricarbonyl and cyclopentadienylrhenium tricarbonyl with mercuric acetate (5 equiv) in refluxing 1,2-dichloroethane for 4 h afforded pentakis-(acetoxymercurio)cyclopentadienyl)manganese tricarbonyl (73%) and (pentakis(acetoxymercurio)cyclopentadienyl)rhenium tricarbonyl (90%) as pale yellow powders. These new complexes were characterized by H-1 NMR, infrared spectroscopy, and microanalysis. Reaction of (pentakis(acetoxymercurio)cyclopentadienyl)manganese tricarbonyl with cupric chloride in refluxing acetone, cupric bromide in refluxing acetone, and potassium triiodide in water afforded (pentachlorocyclopentadienyl)manganese tricarbonyl (45%), (pentabromocyclopentadienyl)manganese tricarbonyl (44%), and (pentaiodocyclopentadienyl)manganese tricarbonyl (19%). Treatment of (pentakis(acetoxymercurio)cyclopentadienyl)rhenium tricarbonyl with the above halogenating agents afforded only unidentified decomposition products. The structure of (pentaiodocyclopentadienyl)manganese tricarbonyl was determined, showing that this compound crystallized in the triclinic space group P1BAR, with cell dimensions a = 13.547(4) angstrom, b = 14.360(3) angstrom, c = 16.729(4) angstrom, alpha = 90.95(2)-degrees, beta = 89.91(2)-degrees, gamma = 103.77(2)-degrees, V = 3160(l) angstrom3, and Z = 8.

  DOI：

  10.1021/om00017a049