di-μ-iodo-bis[iodo(η(6)-para-cymene)ruthenium(II)]toluene solvate | 257906-50-6

• 英文名称: di-μ-iodo-bis[iodo(η(6)-para-cymene)ruthenium(II)]toluene solvate
• CAS: 257906-50-6
• 化学式: C₇H₈*C₂₀H₂₈I₄Ru₂
• 分子量: 1070.34
• InChiKey: BAVLHEARGFZWAZ-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 sodium iodide 在 Ag₂SO₄ 作用下， 以 水 为溶剂， 以76%的产率得到di-μ-iodo-bis[iodo(η(6)-para-cymene)ruthenium(II)]toluene solvate
  参考文献：
  名称：

  Di-μ-bromo-bis[bromo(η⁶-para-cymene)ruthenium(II)] benzene solvate and di-μ-iodo-bis[(η⁶-para-cymene)iodoruthenium(II)] toluene solvate

  摘要：

  The homologous title molecules, [Ru2Br4(C10H14)(2)]. C6H6, (1), and [Ru2I4(C10H14)(2)]. C7H8, (2), consist of arene-ruthenium moieties [Ru-to-ring distances of 1.655 (2) Angstrom in (1) and 1.673(3) Angstrom in (2)] with a terminal halogen ligand and [Ru-Br 2.548 (1) Angstrom in (1) and Ru-I 2.726(1) Angstrom in (2)], held together by two symmetrical halogen bridges [Ru-Br 2.575(1) Angstrom in (1) and Ru-I 2.736(1) Angstrom in (2)]. The arene rings are planar and parallel to each other, and the terminal halogen ligands are coordinated to rurthenium trans with respect to each other. Both molecules possess C-i symmetry.

  DOI：

  10.1107/s0108270199010410