Thermal decomposition of lanthanide and actinide tetrafluorides
作者:John K. Gibson、Richard G. Haire
DOI:10.1016/0040-6031(88)87164-8
日期:1988.10
The thermalstabilities of several lanthanide/actinide tetrafluorides have been studied using mass spectrometry to monitor the gaseous decomposition products, and powder X-ray diffraction (XRD) to identify solid products. The tetrafluorides, TbF/sub 4/, CmF/sub 4/, and AmF/sub 4/, have been found to thermally decompose to their respective solid trifluorides with accompanying release of fluorine, while