Si(fluoride)4(1,10-phenanthroline) | 19584-61-3

• 英文名称: Si(fluoride)4(1,10-phenanthroline)
• 英文别名: SiF4(Phen)
• CAS: 19584-61-3
• 化学式: C₁₂H₈F₄N₂Si
• 分子量: 284.288
• InChiKey: HLGXSXTVIMKWGJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 silicon tetrafluoride 以 四氯化碳 为溶剂， 生成 Si(fluoride)4(1,10-phenanthroline)
  参考文献：
  名称：

  Ostapchuk, L. V.; Gavrilova, L. A.; Gel'mbol'dt, V. O., Russian Journal of Inorganic Chemistry, 1988, vol. 33, p. 813 - 815

  摘要：

  DOI：

文献信息

• Perfluoropropylene oxide as a reagent for the synthesis of germanium, titanium, tin, and zirconium fluorides
  作者：S. A. Lermontov、A. N. Malkova、E. Kh. Lermontova、A. V. Churakov

  DOI：10.1134/s1070363210090185

  日期：2010.9

  fluoride alcohol complexes by reaction of the metal oxides with a solution of perfluoropropylene oxide in methanol is developed. The reaction of the complexes obtained with ligands (L = 1,10-phenanthroline or dimethyl sulfoxide) was studied, and the structure of the obtained compounds was determined. A new route to the synthesis of 1-fluorogermatrane is developed.

  开发了一种通过金属氧化物与全氟环氧丙烷在甲醇中的反应制备锗，钛，锡和锆氟化锆醇配合物的新方法。研究了与配体（L = 1,10-菲咯啉或二甲基亚砜）形成的配合物的反应，并确定了所获化合物的结构。开发了一种合成1-氟锗烷的新途径。
• Interaction between hydrofluorosilicic acid and 1,10-phenanthroline: Hydrolytic stability of chelate complexes of silicon tetrafluoride with bidentate N-donors
  作者：V. O. Gel’mbol’dt、V. Yu. Anisimov、M. S. Fonar’

  DOI：10.1134/s0036023616070056

  日期：2016.7

  Hexafluorosilicate (LH2)SiF6 and the cis-[SiF4(L)] chelate complex characterized by F-19 NMR are products of reaction between hydrofluorosilicic acid and 1,10-phenanthroline (L). XRD findings show that the structure of (LH2)SiF6 is stabilized by NH center dot center dot center dot F hydrogen bonds (N center dot center dot center dot F 2.618(4), 2.676(4) ) and CH center dot center dot center dot F contacts. The relative resistance of the cis-[SiF4(L)] complex to hydrolysis is associated with the chelate effect.