2-ruthenocenylethynylcobaltocenium hexafluorophosphate | 872088-25-0

• 英文名称: 2-ruthenocenylethynylcobaltocenium hexafluorophosphate
• CAS: 872088-25-0
• 化学式: C₂₂H₁₈CoRu*F₆P
• 分子量: 587.412
• InChiKey: HJVSQKUZBFTHGS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  盐酸 、 2-ruthenocenylethynylcobaltocenium hexafluorophosphate 、 水 在 Amberlite IRA-410 (chloride form) 作用下， 以 甲醇 、 水 为溶剂， 生成 2-ruthenocenylethynylcobaltocenium chloride
  参考文献：
  名称：

  The (E)-2-Ferrocenylethenylcobaltocenium Cation. A Missing Link in Heteronuclear Bimetallocene-Based Donor−Acceptor Conjugate Chemistry Exhibiting Irregular Solvatochromism

  摘要：

  The new heteronuclear ethene-bridged himetallocene ferrocenylethenylcobaltocenium cation (fec-ene-coc(+)), as hexafluorophosphate and chloride, was prepared by Knoevenagel condensation of methylcobaltocenium PF6 and ferrocenecarbaldehyde. The chloride was obtained by anion exchange. X-ray crystal structure, cyclic voltammetry, and detailed solvatochromism data are reported and compared to those of related bimetallocenes, namely, the ethyne-bridged fec-yne-coc(+), the directly linked fec-coc(+), the new ethene-bridged ruc-ene-coc(+), and the ethyne-bridged ruc-yne-coc(+), as well as related termetallocenes.

  DOI：

  10.1021/om050431w