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    首页 分子通 按分子结构分类 有机化合物 有机盐 有机金属盐

    有机金属盐

    有机金属盐

    有机金属化合物是指含有碳-金属键（C-M）的化合物，其中M代表过渡金属、碱土金属或其他金属元素。这些化合物通常由一个或多个有机配体与金属中心结合形成。当这些有机金属化合物与离子性较强的无机阳离子组合时，就形成了有机金属盐。

    特点
    1. 结构多样：有机金属盐的分子可以具有高度复杂和多样化的设计，包括平面、链状或网状结构。
    2. 反应性高：由于金属中心的存在，这些化合物通常表现出较高的化学活性，能够参与多种催化过程以及合成反应。
    3. 应用广泛：它们在材料科学（如催化剂）、药物设计与制备、有机合成等领域有着重要应用。
    应用领域
    • 催化剂: 一些有机金属盐作为高效的工业催化剂，在聚合物合成、石油裂解等方面发挥着重要作用。例如，钛络合物被广泛用于聚乙烯的生产。
    • 药物和农药: 合成过程中使用的过渡金属配合物可以作为前体来制备新的药物分子或农药成分。
    • 材料科学: 利用有机金属化合物的独特性质开发出新型功能材料。
    例子
    • 格氏试剂（Grignard reagents）：含有镁和碳的化合物，是极重要的合成工具，在有机化学中被用来生成醇、卤化物等产物。
    • 二茂铁配合物: Fe(C5H5)2类配合物是一种经典的有机金属化合物，具有良好的抗氧化性能，并且在生物催化领域有重要应用。

    综上所述，有机金属盐因其独特的结构和性质，在科学研究及实际生产中扮演着不可或缺的角色。

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— bis(O-isopropyldithiocarbonato)platinum(II) 63374-82-3 C8H14O2PtS4
    bis(O-isopropyldithiocarbonato)platinum(II)
    —— (Dimethylamine)trihydroboron 74-94-2 C2H6BN-
    (Dimethylamine)trihydroboron
    —— Azane;6-azanidylhexylazanide;platinum(2+);dichloride —— C6H26Cl2N6Pt2
    Azane;6-azanidylhexylazanide;platinum(2+);dichloride
    —— hafnium;methane —— CH4Hf3
    hafnium;methane
    —— azanide;cyclohexylazanide;dichloroplatinum(2+);dihydrate —— C6H18Cl2N2O2Pt
    azanide;cyclohexylazanide;dichloroplatinum(2+);dihydrate
    —— Cycloocta-1,5-diene;rhodium(2+);dichloride —— C8H12Cl2Rh
    Cycloocta-1,5-diene;rhodium(2+);dichloride
    —— Diethynylcarbamodithioic acid;manganese(2+) —— C5H3MnNS2+2
    Diethynylcarbamodithioic acid;manganese(2+)
    —— Nickel,2'-(1-methyl-1,2-ethanediylidene)bis[hydrazinecarboximidamidato]](2-)-N,N'',N2,N2']- —— C5H10N8Ni
    Nickel,2'-(1-methyl-1,2-ethanediylidene)bis[hydrazinecarboximidamidato]](2-)-N,N'',N2,N2']-
    —— Aluminum;magnesium;ethanolate;2-methanidylpropane;titanium(4+);tetrachloride —— C16H37AlCl4MgO2Ti
    Aluminum;magnesium;ethanolate;2-methanidylpropane;titanium(4+);tetrachloride
    —— Aluminum;magnesium;ethanolate;prop-1-ene;titanium(4+);tetrachloride —— C13H25AlCl4MgO2Ti
    Aluminum;magnesium;ethanolate;prop-1-ene;titanium(4+);tetrachloride
    —— Oxomolybdenum;propane-1,3-dithiolate;azide —— C9H18Mo2N3O2S6-7
    Oxomolybdenum;propane-1,3-dithiolate;azide
    —— 2-Aminoethanethiolate;iridium(3+);rhodium(3+) —— C12H36Ir2N6RhS6+3
    2-Aminoethanethiolate;iridium(3+);rhodium(3+)
    —— 2-Di(propan-2-yl)phosphaniumylethyl-di(propan-2-yl)phosphanium;ethanethiolate;nickel;sulfanide —— C30H74Ni2P4S2+2
    2-Di(propan-2-yl)phosphaniumylethyl-di(propan-2-yl)phosphanium;ethanethiolate;nickel;sulfanide
    —— Carbon monoxide;osmium;sulfanide —— C9H2O9Os3S2-2
    Carbon monoxide;osmium;sulfanide
    —— Bromonickel;trimethoxyphosphanium —— C12H40BrNiO12P4+4
    Bromonickel;trimethoxyphosphanium
    —— Molybdenum;trimethylphosphanium —— C15H50MoP5+5
    Molybdenum;trimethylphosphanium
    —— Azane;butane-1,4-diamine;platinum(4+) —— C4H24N6Pt2+8
    Azane;butane-1,4-diamine;platinum(4+)
    —— Chloroplatinum(1+);ditert-butyl(5-ditert-butylphosphaniumylpent-2-enyl)phosphanium —— C21H45ClP2Pt+2
    Chloroplatinum(1+);ditert-butyl(5-ditert-butylphosphaniumylpent-2-enyl)phosphanium
    —— 2-Cyclohexylideneethylideneruthenium(1+);ditert-butyl(ditert-butylphosphaniumylmethyl)phosphanium;dichloronio(2-cyclohexylideneethylidene)ruthenium —— C50H106Cl2P4Ru2+7
    2-Cyclohexylideneethylideneruthenium(1+);ditert-butyl(ditert-butylphosphaniumylmethyl)phosphanium;dichloronio(2-cyclohexylideneethylidene)ruthenium
    —— Ditert-butyl(2-ditert-butylphosphaniumylethyl)phosphanium;dichloronio(3-methylbut-2-enylidene)ruthenium;3-methylbut-2-enylideneruthenium(1+) —— C46H102Cl2P4Ru2+7
    Ditert-butyl(2-ditert-butylphosphaniumylethyl)phosphanium;dichloronio(3-methylbut-2-enylidene)ruthenium;3-methylbut-2-enylideneruthenium(1+)
    —— Ditert-butyl(ditert-butylphosphaniumylmethyl)phosphanium;dichloro(2-cyclohexylideneethylidene)ruthenium —— C25H52Cl2P2Ru+2
    Ditert-butyl(ditert-butylphosphaniumylmethyl)phosphanium;dichloro(2-cyclohexylideneethylidene)ruthenium
    —— Trisilver;azanide;ethane-1,2-diamine —— C2H10Ag3N3+2
    Trisilver;azanide;ethane-1,2-diamine
    —— Diethoxy(dihydroxy)phosphanium;silver;trihydrate —— C4H18Ag4O7P+
    Diethoxy(dihydroxy)phosphanium;silver;trihydrate
    —— Cobalt;dimethylaminomethanedithiolate;trimethylphosphanium —— C12H34CoN2P2S4-2
    Cobalt;dimethylaminomethanedithiolate;trimethylphosphanium
    —— Azanide;trichlororuthenium;trimethoxyphosphanium —— C6H22Cl3NO6P2Ru+
    Azanide;trichlororuthenium;trimethoxyphosphanium
    —— Bromoplatinum(1+);prop-1-ene;triethylphosphanium —— C15H37BrP2Pt+2
    Bromoplatinum(1+);prop-1-ene;triethylphosphanium
    —— Ethane-1,1-diol;nitroxyl anion;platinum —— C12H36N2O14Pt4-2
    Ethane-1,1-diol;nitroxyl anion;platinum
    —— Azane;bromocopper;copper;ethane-1,1-diol;hydrate —— C4H26Br2Cu3N4O5
    Azane;bromocopper;copper;ethane-1,1-diol;hydrate
    —— [amino(azanidylidene)methyl]-[(Z)-[(1Z)-1-[amino(azanidylidene)methyl]azanidyliminopropan-2-ylidene]amino]azanide;chloro(chloronio)palladium;chloropalladium(1+) —— C5H9Cl3N8Pd2-2
    [amino(azanidylidene)methyl]-[(Z)-[(1Z)-1-[amino(azanidylidene)methyl]azanidyliminopropan-2-ylidene]amino]azanide;chloro(chloronio)palladium;chloropalladium(1+)
    —— Azanide;chloro(chloronio)copper;chlorocopper(1+);chloroniocopper;copper(1+);2-ethylpyrazine-1,4-diide —— C6H12Cl4Cu5N3+2
    Azanide;chloro(chloronio)copper;chlorocopper(1+);chloroniocopper;copper(1+);2-ethylpyrazine-1,4-diide
    —— Boranyl(triethyl)phosphanium —— C6H17BP+
    Boranyl(triethyl)phosphanium
    —— Dichloro(cyclohexylideneazaniumylidene)osmium;tri(propan-2-yl)phosphanium —— C24H54Cl2NOsP2+3
    Dichloro(cyclohexylideneazaniumylidene)osmium;tri(propan-2-yl)phosphanium
    —— (Bromomethyl)germane —— CH2BrGe
    (Bromomethyl)germane
    —— Chloro(dichloronio)platinum;chloroplatinum;tributylphosphanium —— C24H58Cl4P2Pt2+4
    Chloro(dichloronio)platinum;chloroplatinum;tributylphosphanium
    —— 1-Tetracarbonylchromium-2-tetracarbonylmolybdenum-tetramethyldiphosphine —— C12H14CrMoO8P2+2
    1-Tetracarbonylchromium-2-tetracarbonylmolybdenum-tetramethyldiphosphine
    —— Pentanoic acid, di(tert-butyl)silyl ester —— C13H27O2Si
    Pentanoic acid, di(tert-butyl)silyl ester
    —— Difluoro(propylamino)phosphanium;nickel —— C12H36F8N4NiP4+4
    Difluoro(propylamino)phosphanium;nickel
    —— Silane, (silylmethyl)[(trimethylsilyl)methyl]- —— C5H13Si3
    Silane, (silylmethyl)[(trimethylsilyl)methyl]-
    —— Dichloroiron;di(propan-2-yl)phosphaniumylmethyl-di(propan-2-yl)phosphanium —— C13H32Cl2FeP2+2
    Dichloroiron;di(propan-2-yl)phosphaniumylmethyl-di(propan-2-yl)phosphanium
    —— Dibromoiron;2-di(propan-2-yl)phosphaniumylethyl-di(propan-2-yl)phosphanium —— C14H34Br2FeP2+2
    Dibromoiron;2-di(propan-2-yl)phosphaniumylethyl-di(propan-2-yl)phosphanium
    —— 1,3,5-Trisilahexane —— C3H7Si3
    1,3,5-Trisilahexane
    —— Carbon monoxide;trimethylphosphanium;tungsten —— C8H10O5PW+
    Carbon monoxide;trimethylphosphanium;tungsten
    —— Carbon monoxide;tris(dimethylamino)phosphanium;tungsten —— C11H19N3O5PW+
    Carbon monoxide;tris(dimethylamino)phosphanium;tungsten
    —— Propanoic acid, di(tert-butyl)silyl ester —— C11H23O2Si
    Propanoic acid, di(tert-butyl)silyl ester
    —— Silane, (fluoromethyl)dimethyl- —— C3H8FSi
    Silane, (fluoromethyl)dimethyl-
    —— Carbon monoxide;dimethylphosphanium;iron —— C10H16Fe2O6P2+2
    Carbon monoxide;dimethylphosphanium;iron
    —— Aluminum;ethane;dichloride —— C2H5AlCl2
    Aluminum;ethane;dichloride
    —— calcium;[(E)-1-chloropropylideneamino] N-ethylcarbamate;dichloride —— C6H11CaCl3N2O2
    calcium;[(E)-1-chloropropylideneamino] N-ethylcarbamate;dichloride
    —— cyclopentane;iron;methyl (E)-3-cyclopentylprop-2-enoate —— C14H14FeO2-10
    cyclopentane;iron;methyl (E)-3-cyclopentylprop-2-enoate
    —— Cyclopropane, 2-hexylidene-1,1-bis(trimethylsilyl)- —— C15H32Si2
    Cyclopropane, 2-hexylidene-1,1-bis(trimethylsilyl)-