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    首页 分子通 按分子结构分类 有机化合物 有机盐 有机金属盐

    有机金属盐

    有机金属盐

    有机金属化合物是指含有碳-金属键（C-M）的化合物，其中M代表过渡金属、碱土金属或其他金属元素。这些化合物通常由一个或多个有机配体与金属中心结合形成。当这些有机金属化合物与离子性较强的无机阳离子组合时，就形成了有机金属盐。

    特点
    1. 结构多样：有机金属盐的分子可以具有高度复杂和多样化的设计，包括平面、链状或网状结构。
    2. 反应性高：由于金属中心的存在，这些化合物通常表现出较高的化学活性，能够参与多种催化过程以及合成反应。
    3. 应用广泛：它们在材料科学（如催化剂）、药物设计与制备、有机合成等领域有着重要应用。
    应用领域
    • 催化剂: 一些有机金属盐作为高效的工业催化剂，在聚合物合成、石油裂解等方面发挥着重要作用。例如，钛络合物被广泛用于聚乙烯的生产。
    • 药物和农药: 合成过程中使用的过渡金属配合物可以作为前体来制备新的药物分子或农药成分。
    • 材料科学: 利用有机金属化合物的独特性质开发出新型功能材料。
    例子
    • 格氏试剂（Grignard reagents）：含有镁和碳的化合物，是极重要的合成工具，在有机化学中被用来生成醇、卤化物等产物。
    • 二茂铁配合物: Fe(C5H5)2类配合物是一种经典的有机金属化合物，具有良好的抗氧化性能，并且在生物催化领域有重要应用。

    综上所述，有机金属盐因其独特的结构和性质，在科学研究及实际生产中扮演着不可或缺的角色。

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2,2-Dimethylpropylidene(oxo)tungsten;trimethylphosphanium;dihydrochloride —— C11H32Cl2OP2W+2
    2,2-Dimethylpropylidene(oxo)tungsten;trimethylphosphanium;dihydrochloride
    —— Bromonickel;methyl-[2-[methyl(3-methylphosphanylpropyl)phosphaniumyl]ethyl]-(3-methylphosphanylpropyl)phosphanium —— C12H32BrNiP4+2
    Bromonickel;methyl-[2-[methyl(3-methylphosphanylpropyl)phosphaniumyl]ethyl]-(3-methylphosphanylpropyl)phosphanium
    —— Azorous acid;copper;ethane-1,2-diamine;hydroxylamine —— C8H41Cu2N11O7
    Azorous acid;copper;ethane-1,2-diamine;hydroxylamine
    —— Dichloromolybdenum;trimethylphosphanium —— C12H40Cl4Mo2P4+4
    Dichloromolybdenum;trimethylphosphanium
    —— 2-Di(propan-2-yl)phosphaniumylethyl-di(propan-2-yl)phosphanium;nickel —— C28H68NiP4+4
    2-Di(propan-2-yl)phosphaniumylethyl-di(propan-2-yl)phosphanium;nickel
    —— Diethylphosphane;iodoplatinum(1+);triethyl(methylidene)-lambda5-phosphane;triethylphosphanium —— C17H44IP3Pt+2
    Diethylphosphane;iodoplatinum(1+);triethyl(methylidene)-lambda5-phosphane;triethylphosphanium
    —— Butane-2,3-diamine;cobalt(3+) —— C12H36CoN6+3
    Butane-2,3-diamine;cobalt(3+)
    —— N-[amino(oxido)methylidene]carbamimidate;copper;ethane-1,2-diamine —— C4H11CuN5O2-2
    N-[amino(oxido)methylidene]carbamimidate;copper;ethane-1,2-diamine
    —— Azonous acid;ethane-1,2-diamine;ZINC —— C4H19N5O2Zn
    Azonous acid;ethane-1,2-diamine;ZINC
    —— dichlorocadmium;tris(dimethylamino)-hydroxyphosphanium —— C12H38CdCl2N6O2P2+2
    dichlorocadmium;tris(dimethylamino)-hydroxyphosphanium
    —— 2-Amino-1-hydroxyethanolate;dichlorocopper —— C4H12Cl2CuN2O4-2
    2-Amino-1-hydroxyethanolate;dichlorocopper
    —— Cyclopropyl-[3-diethylphosphaniumyl-2-(diethylphosphaniumylmethyl)-2-methylpropyl]-ethylphosphanium;[3-diethylphosphaniumyl-2-(diethylphosphaniumylmethyl)-2-methylpropyl]-diethylphosphanium;iron;trichloronioiron —— C35H87Cl3Fe2P6+9
    Cyclopropyl-[3-diethylphosphaniumyl-2-(diethylphosphaniumylmethyl)-2-methylpropyl]-ethylphosphanium;[3-diethylphosphaniumyl-2-(diethylphosphaniumylmethyl)-2-methylpropyl]-diethylphosphanium;iron;trichloronioiron
    —— Methanone;palladium;palladium(2+);thallium(1+);triethylphosphanium —— C63H153O9P9Pd12Tl2+8
    Methanone;palladium;palladium(2+);thallium(1+);triethylphosphanium
    —— Dichloroiron;2-dimethylphosphaniumylethyl(dimethyl)phosphanium —— C12H36Cl2FeP4+4
    Dichloroiron;2-dimethylphosphaniumylethyl(dimethyl)phosphanium
    —— Cobalt;propane-1,2,3-triamine —— C6H22CoN6
    Cobalt;propane-1,2,3-triamine
    —— Butyl(dipropyl)phosphanium;chloropalladium(1+);1,4-di(ethyl)cyclohexane;tributylphosphanium —— C54H122Cl2P4Pd2+4
    Butyl(dipropyl)phosphanium;chloropalladium(1+);1,4-di(ethyl)cyclohexane;tributylphosphanium
    —— Dichloroiron;2-diethylphosphaniumylethyl(diethyl)phosphanium —— C20H52Cl2FeP4+4
    Dichloroiron;2-diethylphosphaniumylethyl(diethyl)phosphanium
    —— 2-Di(propan-2-yl)phosphaniumylethyl-di(propan-2-yl)phosphanium;ethane-1,2-dithiolate;nickel(2+) —— C16H38NiP2S2+2
    2-Di(propan-2-yl)phosphaniumylethyl-di(propan-2-yl)phosphanium;ethane-1,2-dithiolate;nickel(2+)
    —— Copper;dioxidanium;ethane-1,2-diamine —— C4H22CuN4O2+4
    Copper;dioxidanium;ethane-1,2-diamine
    —— Azorous acid;cobalt;2,2,4,4,6,6,8,8,10,10,12,12,14,14,16,16-hexadecamethyl-1,3,5,11-tetraza-7,9,13,15-tetrazanida-8lambda5,14lambda5-diphospha-2,4,6,10,12,16-hexaphosphoniacyclohexadecane —— C16H57CoN9O3P8+2
    Azorous acid;cobalt;2,2,4,4,6,6,8,8,10,10,12,12,14,14,16,16-hexadecamethyl-1,3,5,11-tetraza-7,9,13,15-tetrazanida-8lambda5,14lambda5-diphospha-2,4,6,10,12,16-hexaphosphoniacyclohexadecane
    —— Buta-1,3-diene;2-dimethylphosphaniumylethyl(dimethyl)phosphanium;hafnium —— C14H30HfP2+2
    Buta-1,3-diene;2-dimethylphosphaniumylethyl(dimethyl)phosphanium;hafnium
    —— Dibromoiridium(1+);ethane;trimethylphosphanium —— C11H35Br2IrP3+3
    Dibromoiridium(1+);ethane;trimethylphosphanium
    —— 2-Di(propan-2-yl)phosphaniumylethyl-di(propan-2-yl)phosphanium;nickel(2+);propane-1,3-dithiolate —— C17H40NiP2S2+2
    2-Di(propan-2-yl)phosphaniumylethyl-di(propan-2-yl)phosphanium;nickel(2+);propane-1,3-dithiolate
    —— Butyl-di(propan-2-yl)phosphanium;dichloronickel —— C20H48Cl2NiP2+2
    Butyl-di(propan-2-yl)phosphanium;dichloronickel
    —— N'-amino-N-methylcarbamimidothioate;nickel —— C4H12N6NiS2-2
    N'-amino-N-methylcarbamimidothioate;nickel
    —— 2-[Bis(4-hydroxybutyl)phosphaniumyl]ethyl-bis(4-hydroxybutyl)phosphanium;dichloroiron(1+) —— C36H84Cl2FeO8P4+5
    2-[Bis(4-hydroxybutyl)phosphaniumyl]ethyl-bis(4-hydroxybutyl)phosphanium;dichloroiron(1+)
    —— Methanone;rhodium;rhodium(2+);tri(propan-2-yloxy)phosphanium —— C38H90O14P4Rh2+4
    Methanone;rhodium;rhodium(2+);tri(propan-2-yloxy)phosphanium
    —— Azane;dichloroplatinum;trimethylphosphanium —— C3H13Cl2NPPt+
    Azane;dichloroplatinum;trimethylphosphanium
    —— Azane;fluorochromium(2+);propane-1,3-diamine —— C6H23CrFN5+2
    Azane;fluorochromium(2+);propane-1,3-diamine
    —— Dibromo(dichloro)platinum;triethylphosphanium —— C12H32Br2Cl2P2Pt+2
    Dibromo(dichloro)platinum;triethylphosphanium
    —— 3-Azanidylpropylazanide;iodonioplatinum;iodoplatinum —— C12H34I3N8Pt3-6
    3-Azanidylpropylazanide;iodonioplatinum;iodoplatinum
    —— 2-Azanidylethylazanide;dichloronionickel(1+);nickel —— C8H26Cl2N8Ni2-5
    2-Azanidylethylazanide;dichloronionickel(1+);nickel
    —— cis-{CrF2en2}(1+) —— C4H16CrF2N4
    cis-{CrF2en2}(1+)
    —— 2-[Bis(4-hydroxybutyl)phosphaniumyl]ethyl-bis(4-hydroxybutyl)phosphanium;dichloroiron —— C36H84Cl2FeO8P4+4
    2-[Bis(4-hydroxybutyl)phosphaniumyl]ethyl-bis(4-hydroxybutyl)phosphanium;dichloroiron
    —— Ditert-butyl(propan-2-yl)phosphanium;platinum;tritert-butylphosphanium —— C35H82P3Pt3+3
    Ditert-butyl(propan-2-yl)phosphanium;platinum;tritert-butylphosphanium
    —— Cobalt;dimethylphosphanium;dimethylphosphaniumylmethyl(dimethyl)phosphanium;trimethylphosphanium —— C18H60Co2P7+7
    Cobalt;dimethylphosphanium;dimethylphosphaniumylmethyl(dimethyl)phosphanium;trimethylphosphanium
    —— N'-(dimethylamino)-N-methylcarbamimidothioate;nickel —— C8H20N6NiS2-2
    N'-(dimethylamino)-N-methylcarbamimidothioate;nickel
    —— Azanide;dichloroplatinum;trimethylphosphanium —— C3H12Cl2NPPt
    Azanide;dichloroplatinum;trimethylphosphanium
    —— N'-(dimethylamino)-N-ethylcarbamimidothioate;nickel —— C10H24N6NiS2-2
    N'-(dimethylamino)-N-ethylcarbamimidothioate;nickel
    —— dichlororuthenium(2+);methanol;tricyclohexylphosphanium —— C38H74Cl2O2P2Ru+2
    dichlororuthenium(2+);methanol;tricyclohexylphosphanium
    —— Azanide;ethane-1,2-diamine;nickel;octacyanide —— C16H34N17Ni5-9
    Azanide;ethane-1,2-diamine;nickel;octacyanide
    —— methanol;ruthenium(2+) dihydride;tricyclohexylphosphanium —— C38H76O2P2Ru+2
    methanol;ruthenium(2+) dihydride;tricyclohexylphosphanium
    —— 2-Aminoethanethiolate;oxo(oxorheniooxy)rhenium —— C8H24N4O3Re2S4-4
    2-Aminoethanethiolate;oxo(oxorheniooxy)rhenium
    —— methanol;rhodium(2+);tris[(2,6-dimethylcyclohexyl)oxy]phosphanium —— C50H98O8P2Rh+2
    methanol;rhodium(2+);tris[(2,6-dimethylcyclohexyl)oxy]phosphanium
    —— [Tert-butyl-bis[[hydroxy(dimethyl)phosphaniumyl]methyl]silyl]methyl-hydroxy-dimethylphosphanium —— C13H36O3P3Si+3
    [Tert-butyl-bis[[hydroxy(dimethyl)phosphaniumyl]methyl]silyl]methyl-hydroxy-dimethylphosphanium
    —— Azane;cobalt(3+);pentane-2,4-diamine —— C5H26CoN6+3
    Azane;cobalt(3+);pentane-2,4-diamine
    —— Azanide;cobalt;ethane-1,2-diamine;hydrogen peroxide —— C4H28Co2N9O2-5
    Azanide;cobalt;ethane-1,2-diamine;hydrogen peroxide
    —— (2-Aminocyclopentyl)azanide;cyclopentane-1,2-diamine;dichlorocobalt(1+) —— C10H23Cl2CoN4
    (2-Aminocyclopentyl)azanide;cyclopentane-1,2-diamine;dichlorocobalt(1+)
    —— Azane;4-azanidylpentan-2-ylazanide;platinum(2+) —— C10H30N6Pt-2
    Azane;4-azanidylpentan-2-ylazanide;platinum(2+)
    —— Dichlororhodium;tris[(2,6-dimethylcyclohexyl)oxy]phosphanium —— C48H92Cl2O6P2Rh+2
    Dichlororhodium;tris[(2,6-dimethylcyclohexyl)oxy]phosphanium