[(2,2'-bipyridine)2(H2O)Ru(III)ORu(III)(OH2)(2,2'-bipyridine)2](ClO4)4 * 2 H2O | 96364-20-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [(2,2'-bipyridine)2(H2O)Ru(III)ORu(III)(OH2)(2,2'-bipyridine)2](ClO4)4 * 2 H2O
• 英文别名: diaquatetetrakis(2,2'-bipyridine)-μ-oxodiruthenium(III) perchlorate；{(2,2'-bipyridine)2(OH2)RuORu(OH2)(2,2'-bipyridine)2}(ClO4)4*2H2O；{[Ru^III(H₂O)(bipyridine)₂]₂(μ-O)}·4ClO₄⁻·2H₂O；{[Ru^III(H₂O)(bpy)₂]₂(μ-O)}·4ClO₄⁻·2H₂O；[Ru(III)(2,2'-bipiridine)2(H2O)]2(μ-O)(ClO4)4*2H2O
• CAS: 96364-20-4
• 化学式: C₄₀H₃₆N₈O₃Ru₂*4ClO₄*2H₂O
• 分子量: 1312.75
• InChiKey: XPEUPRZNBAFZRP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  sodium perchlorate monohydrate 、 [(2,2'-bipyridine)2(H2O)Ru(III)ORu(III)(OH2)(2,2'-bipyridine)2](ClO4)4 * 2 H2O 在 C₅H₅N 作用下， 以 吡啶 为溶剂， 以75%的产率得到{(2,2'-bipyridine)2(pyridine)RuORu(pyridine)(2,2'-bipyridine)2}(ClO4)4*4H2O
  参考文献：
  名称：

  Doppelt, Pascal; Meyer, Thomas J., Inorganic Chemistry, 1987, vol. 26, # 13, p. 2027 - 2034

  摘要：

  DOI：
• 作为产物：
  描述：

  顺-双(2,2-二吡啶)二氯化钌(II) 水合物 、 sodium perchlorate 在 双氧水 、 silver nitrate 作用下， 以 水 为溶剂， 以9%的产率得到bis[(μ-oxo)-cis-aquabis(bipyridine)ruthenium]-trans-bis(bipyridine)ruthenium(6+) perchlorate heptahydrate
  参考文献：
  名称：

  Geselowitz, Daniel A.; Kutner, Wlodzimierz; Meyer, Thomas J., Inorganic Chemistry, 1986, vol. 25, # 12, p. 2015 - 2023

  摘要：

  DOI：

文献信息

• Structural and Resonance Raman Studies of an Oxygen-Evolving Catalyst. Crystal Structure of [(bpy)₂(H₂O)Ru^IIIORu^IV(OH)(bpy)₂](ClO₄)₄
  作者：Jon R. Schoonover、JinFeng Ni、Lee Roecker、Peter S. White、Thomas J. Meyer

  DOI：10.1021/ic960348o

  日期：1996.1.1

  The oxidized form of the blue dimer water oxidation catalyst [(bpy)(2)(H2O)(RuORuIV)-O-III(OH)(bpy)(2)](ClO4)(4) (bpy is 2,2'-bipyridine) has been characterized structurally by X-ray crystallography. Comparisons with [(bpy)(2)(H2O)Ru-III- ORuIII(OH2)(bpy)(2)](ClO4)(4) . 2H(2)O, [(bpy)(2)(ClRuORuCl)-O-III-Cl-IV(bpy)(2)](ClO4)(3) . H2O, and [(tpy)(bpy)(OsOOsIV)-O-III(bpy)(tpy)]Na(ClO4)(6) . 3H(2)O (tpy is 2,2':6',2 ''-terpyridine) reveal that oxidation of Ru-III-O-Ru-III to Ru-III-O-Ru-IV results in significant structural changes at the mu-oxo bridge. There is an increase toward linearity along M-O-M, a decrease in the M-O bond distances at the bridge, and an increase in the H2O-Ru-O bridge-angle. These changes are discussed in the context of the structural requirements for O ... O coupling and Oz evolution in higher oxidation states. Resonance Raman spectra of these and related complexes reveal that internal ligand vibrations as well as overtone and combination bands of an intense, symmetrical M-O-M stretch at 360-400 cm(-1) contribute significantly to the Raman spectra. Additional M-O-M bands are identified near 800 cm(-1) and, tentatively, near 130 cm(-1). It is not possible to assign bands to Ru-OH2 or Ru-OH stretches; bands at low energy appear to originate from modes that are highly mixed.
• Insights into Decomposition Pathways and Fate of Ru(bpy)₃²⁺ during Photocatalytic Water Oxidation with S₂O₈^2– as Sacrificial Electron Acceptor
  作者：Umme Sarmeen Akhtar、Eunju Lee Tae、Yu Sung Chun、In Chul Hwang、Kyung Byung Yoon

  DOI：10.1021/acscatal.6b02595

  日期：2016.12.2

  The most widely accepted system for homogeneous photocatalytic water oxidation process consists of a water oxidation catalyst, Ru-II(bpy)(3)(2+) as a photopump, and S2O82- as the sacrificial electron acceptor. However, this system is far less than ideal because Ru-II(bpy)(3)(2+) undergoes very rapid decomposition and as a result the process stops before all of the S2O82- is consumed. In this regard its decomposition pathways and the fate of Ru-II(bpy)(3)(2+) should be elucidated to design more efficient photocatalytic water oxidation systems. We found that two pathways exist for decomposition of Ru-II(bpy)(3)(2+) in the light-Ru-II(bpy)(3)2+-S2O82- system. The first is the formation of OH center dot radicals at pH >6 through oxidation of OH- by Ru-III(bpy)(3)(3+) in the dark, which attack the bpy ligand of Ru-II(bpy)(3)(2+). This is a minor, dark decomposition pathway. During irradiation not only Ru-II(bpy)(3)(2+) but also Ru-III(bpy)(3)(3+) becomes photoexcited and the photoexcited Ru-III(bpy)(3)(3+) reacts with S2O82- to produce an intermediate which decomposes into catalytically active Ru mu-oxo dimers when the intermediate concentration is low or into catalytically inactive oligomeric Ru mu-oxo species when the intermediate concentration is high. This is the major, light-induced decomposition pathway. When the Ru-II(bpy)(3)(2+) concentration is low, the light-Ru-II(bpy)(3)(2+)-S2O82- system produces O-2 even in the absence of any added catalysts through the O-2 -producing dark pathway. When the Ru-II(bpy)(3)(2+) concentration is high, the system does not produce O-2 because the overall rate for the light-induced decomposition pathway is much faster than that of the O-2-producing dark pathway.