tetraphenylarsonium nitrate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tetraphenylarsonium nitrate
• 英文别名: tetraphenyl-arsonium; nitrate；Tetraphenyl-arsonium; Nitrat；Tetraphenylarsonium；Tetraphenylarsanium;nitrate
• 化学式: C₂₄H₂₀As*NO₃
• 分子量: 445.349
• InChiKey: JSCRTVJBNUSXEH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.82
• 重原子数：
  29
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  62.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  tetraphenylarsonium nitrate 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Cleavage of the tetrameric palladium(II) complex [Pd4(PPrn3)4(NO2)4(ONO)4]with nucleophiles. X-ray crystal structures of the products trans-[Pd(PPrn3)(NO2)2Cl][As(C6H5)4] and [Pd2(PPrn3)2Cl2(NO2)2]

  摘要：

  DOI：

  10.1016/s0277-5387(00)86498-0

文献信息

• The synthesis and crystal structures of the tetraphenylarsonium salts of [V₂O₃(NO₃)₂X₄]^2–, X = Cl or NO₃
  作者：Stephen Arrowsmith、Michael F. A. Dove、Martin N. Gibbons、Norman Logan、Andrei Batsanov

  DOI：10.1039/c39950001733

  日期：——

  The title compounds, [Ph4As]2[V2O3(NO3)6]1, and [Ph4As]2[V2O3Cl4(NO3)2]2, crystallised from solution in the reaction of tetraphenylarsonium nitrate with VO(NO3)3 and VOCl3, respectively, and the crystal structures of the dianions show that they are structurally related; the octahedral coordination of all vanadium atoms is achieved by two oxygens, a bidentate nitrate and two other monodentate groups, and an unusual feature of compound 2 is the presence of both chlorine and nitrate as ligands on vanadium(V).

  标题化合物 [Ph4As]2[V2O3(NO3)6]1 和 [Ph4As]2[V2O3Cl4( )2]2 分别在硝酸四苯砷与 VO( )3 和 VOCl3 的反应中从溶液中结晶出来，并且二价阴离子的晶体结构表明它们在结构上是相关的；所有钒原子的八面体配位是通过两个氧、一个二齿硝酸盐和另外两个单齿基团实现的，化合物 2 的一个不寻常特征是氯和硝酸盐作为钒 (V) 上的配体。
• The structure of [(C6H5)4As]2[Eu(NO3)5]
  作者：Jean-Claude G. Bünzli、Bernard Klein、Gervais Chapuis、Kurt J. Schenk

  DOI：10.1016/0022-1902(80)80291-0

  日期：1980.1

  The structure of the title compound was solved from single crystal X-ray diffractometer data by Patterson and Fourier methods, and refined by least-squares to conventional RF = 0.046 for 2504 independent observed reflections. The crystals are monoclinic with , β = 103.60(3)°, and Z = 4, space group (No. 15). The Eu(III) ion lies on a twofold axis; it is 10-coordinated and bound to five bidentate nitrato

  标题化合物的结构通过Patterson和Fourier方法由单晶X射线衍射仪数据解析，并针对2504个独立观察到的反射，通过最小二乘法精炼为常规R F = 0.046。晶体是单斜晶体，β= 103.60（3）°，Z = 4，空间群（第15号）。Eu（III）离子位于一个双重轴上。它是10位协调的，并绑定到五个双齿硝酸根基团。EuO的平均距离为2.48（4）Å，OEuO的平均角度为51.4（5）°。配位多面体可以用理想对称的扭曲的二阶方形反棱镜来描述。
• The synthesis, properties and structures of the tetraphenyl-arsonium salts of [V2O3(NO3)2X4]2−, X  Cl or NO3
  作者：Stephen Arrowsmith、Michael F.A. Dove、Norman Logan、Andrei Batsanov

  DOI：10.1016/s0277-5387(97)00377-x

  日期：1998.1

  The complexes [Ph4As](2)[V2O3(NO3)(6)], 1 and [Ph4As](2)[V2O3Cl4(NO3)(2)], 2, crystallise from solution in the reaction of tetraphenylarsonium nitrate with VO(NO3)(3) and VOCl3, respectively. The compounds were characterised by their IR and Raman spectra and single crystal X-ray analysis. Compound 1 crystallises in the triclinic space group P (1) over bar, a = 9.580(1), b = 10.782(2), c = 13.631(2) Angstrom, Z = 1 and R = 0.059, whilst 2 crystallises in the monoclinic space group P2(1)/c, a = 10.1.76(1), b = 17.691(2), c = 13.955(2), Z = 2 and R = 0.034. The crystal structures show that the dianions are related, the vanadium atoms in both species possess distorted octahedral symmetry, this being achieved by one terminal and one bridging oxygen atom, one bidentate nitrate group and four other monodentate ligands. An unusual feature of 1 is the presence of both monodentate and bidentate modes of nitrate coordination whilst 2 is the first example of a mixed halonitrato species of vanadium(V) to be isolated. (C) 1998 Elsevier Science Ltd. All rights reserved.
• Arsonium Compounds. III¹
  作者：F. F. Blicke、S. R. Safir

  DOI：10.1021/ja01851a001

  日期：1941.6