cis-dichlorobis(furfuryl-2-(N-diphenylphosphino)methylamine)platinum(II) | 1347752-18-4

• 英文名称: cis-dichlorobis(furfuryl-2-(N-diphenylphosphino)methylamine)platinum(II)
• CAS: 1347752-18-4
• 化学式: C₃₄H₃₂Cl₂N₂O₂P₂Pt
• 分子量: 828.574
• InChiKey: KPDLNGHVBQAMEZ-UHFFFAOYSA-L

计算性质

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反应信息

• 作为产物：
  描述：

  dichloro( 1,5-cyclooctadiene)platinum(ll) 、 furfuryl-2-(N-diphenylphosphino)methylamine 以 四氢呋喃 为溶剂， 以92.7%的产率得到cis-dichlorobis(furfuryl-2-(N-diphenylphosphino)methylamine)platinum(II)
  参考文献：
  名称：

  Aminophosphine–palladium(II) complexes: Synthsesis, structure and applications in Suzuki and Heck cross-coupling reactions

  摘要：

  Reaction of furfurylamine with 1 or 2 equivalents of PPh2Cl in the presence of Et3N, proceeds under anaerobic conditions in thf to give furfuryl-2-(N-diphenylphosphino)amine, Ph2PNHCH2-C4H3O, 1 and furfuryl-2-(N,N-bis(diphenylphosphino)amine), (Ph2P)(2)NCH2-C4H3O, 2, respectively. The reactions of 1 and 2 with MCl2(cod) (M = Pd, Pt; cod = 1,5-cyclooctadiene) or Pt(CH3)(2)(cod) yield complexes [M(Ph2PNHCH2-C4H3O)(2)Cl-2] (M= Pd 1a, Pt 1b), [Pt(Ph2PNHCH2-C4H3O)(2)(CH3)(2)] (1c), and [M((Ph2P)(2) NCH2-C4H3O)Cl-2] (M= Pd 2a, Pt 2b), [Pt((Ph2P)(2)NCH2-C4H3O)(CH3)(2)] (2c), respectively. All the compounds were isolated as analytically pure substances and characterized by NMR, IR spectroscopy and elemental analysis. Representative solid-state structures of 2a and 2b were also determined by X-ray single crystal diffraction technique. Furthermore, the palladium complexes 1a and 2a were tested and found to be highly active catalysts in the Suzuki coupling and Heck reaction affording biphenyls and trans-stilbenes, respectively. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.07.056