[1,2-ferrocenylene(tin(methyl)2(chloride))(boron(methyl)(chloride)(pyridazine))] | 1262793-85-0

• 英文名称: [1,2-ferrocenylene(tin(methyl)2(chloride))(boron(methyl)(chloride)(pyridazine))]
• 英文别名: [1,2-Fc(SnMe2Cl)(B(Me)(Cl)(N2C4H4))]
• CAS: 1262793-85-0
• 化学式: C₁₇H₂₁BCl₂FeN₂Sn
• 分子量: 509.641
• InChiKey: XVGHJWUOSYKXBC-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  哒嗪 、 1,2-ferrocenediyl(BMeCl))(SnMe2Cl) 以 not given 为溶剂， 生成 [1,2-ferrocenylene(tin(methyl)2(chloride))(boron(methyl)(chloride)(pyridazine))]
  参考文献：
  名称：

  Binding of a 2-pyridyl moiety to a B/Sn bidentate Lewis acid

  摘要：

  Reaction of the bidentate Lewis acid 1,2-Fc(SnMe2Cl)(B(Me)Cl) (1, Fc = 1,2-ferrocenylene) with 2-trimethylstannylpyridine gave a complex (2), in which the 2-pyridyl group forms a bridge between the Lewis acidic tin and boron centers. The structure of 2 was confirmed by multinuclear and two-dimensional NMR, single crystal X-ray diffraction, and elemental analysis. The crystal structure shows that the pyridyl moiety is positioned endo relative to the substituted Cp ring and UV-Vis spectroscopy revealed an enhancement of the ferrocene-centered dd transition in comparison to related complexes with pyridine as a terminal ligand. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.09.010