2-(tert-butylthio)-5-(dimethylamino)benzaldehyde | 1383612-11-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(tert-butylthio)-5-(dimethylamino)benzaldehyde
• 英文别名: 2-Tert-butylsulfanyl-5-(dimethylamino)benzaldehyde
• CAS: 1383612-11-0
• 化学式: C₁₃H₁₉NOS
• 分子量: 237.366
• InChiKey: PIUHDRBSAMHVOI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  45.6
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• [EN] HYDROGENATION OF ESTERS OR CARBONYL GROUPS WITH TETRADENTATE AMINO/IMINO-THIOETHER BASED RUTHENIUM COMPLEXES<br/>[FR] HYDROGÉNATION DE GROUPES ESTERS OU CARBONYLES AVEC DES COMPLEXES DU RUTHÉNIUM À BASE D'AMINO/IMINO-THIOÉTHER TÉTRADENTATE
  申请人：FIRMENICH & CIE

  公开号：WO2012084810A1

  公开（公告）日：2012-06-28

  The present invention relates to the field of catalytic hydrogenation and, more particularly, to the use of specific ruthenium catalysts, or pre-catalysts, in hydrogenation processes for the reduction of ketones and/or aldehydes into the corresponding alcohol respectively. Said catalysts are ruthenium complexes comprising a tetradentate ligand (L4) coordinating the ruthenium with: - two nitrogen atoms, each in the form of a primary or secondary amine (i.e. a NH2 or NH group) or N-alkyl imine functional groups (i.e. a C=N group), and - two sulfur atoms, each in the form of thioether functional groups.

  本发明涉及催化加氢领域，更具体地涉及在氢化过程中使用特定的钌催化剂或前驱体，用于将酮和/或醛还原为相应的醇。所述催化剂是包含四齿配体（L4）的钌络合物，该配体与钌配位，其中：- 两个氮原子，每个以主要或次要胺（即NH2或NH基团）或N-烷基亚胺官能团（即C=N基团）的形式存在，以及- 两个硫原子，每个以硫醚官能团的形式存在。
• HYDROGENATION OF ESTERS OR CARBONYL GROUPS WITH TETRADENTATE AMINO/IMINO-THIOETHER BASED RUTHENIUM COMPLEXES
  申请人：Saudan Sylvia Joyeuse Adélaïde Ada

  公开号：US20130274487A1

  公开（公告）日：2013-10-17

  The present invention relates to the field of catalytic hydrogenation and, more particularly, to the use of specific ruthenium catalysts, or pre-catalysts, in hydrogenation processes for the reduction of ketones and/or aldehydes into the corresponding alcohol respectively. Said catalysts are ruthenium complexes comprising a tetradentate ligand (L4) coordinating the ruthenium with: two nitrogen atoms, each in the form of a primary or secondary amine (i.e. a NH 2 or NH group) or N-alkyl imine functional groups (i.e. a C═N group), and two sulfur atoms, each in the form of thioether functional groups.

  本发明涉及催化加氢领域，更具体地涉及在氢化过程中使用特定的钌催化剂或前驱体，用于将酮和/或醛还原为相应的醇。所述催化剂是包括一个四齿配体（L4）与钌配位的钌络合物，其中：两个氮原子，每个以一种主要或次要胺（即NH2或NH基团）或N-烷基亚胺功能基团（即C═N基团）的形式存在，以及两个硫原子，每个以硫醚功能基团的形式存在。
• US8614345B2
  申请人：——

  公开号：US8614345B2

  公开（公告）日：2013-12-24