[Zn(N-2-[4,6-dimethylpyridyl]-N'-phenylthiourea)4(OAc)2] | 367494-21-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Zn(N-2-[4,6-dimethylpyridyl]-N'-phenylthiourea)4(OAc)2]
• CAS: 367494-21-1
• 化学式: C₆₀H₆₆N₁₂O₄S₄Zn
• 分子量: 1212.92
• InChiKey: RJPBBBFQZYFLEI-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N-2-[4,6-dimethylpyridyl]-N'-phenylthiourea 、 zinc(II) acetate dihydrate 以 乙醇 、 水 为溶剂， 以86%的产率得到[Zn(N-2-[4,6-dimethylpyridyl]-N'-phenylthiourea)4(OAc)2]
  参考文献：
  名称：

  N-2-[4,6-DIMETHYLPYRIDYL]-N′-PHENYLTHIOUREA (HDMPyPt) TRANSITION METAL COMPLEXES

  摘要：

  Several types of new metal complexes of N-2-[4,6-dimethylpyridyl]-N'-phenylthiourea (HDMPyPT) have been prepared from M(OAC)(2) [M = Cu(II), Zn(II), Ni(II), Co(II), UO2(VI)], HAuCl4, Na-2[PdCl4] and metal chlorides [M=Co(II), Sm(III), Nd(III)]. HDMPyPT behaves in a monodentate fashion via the pyridyl nitrogen in all of the complexes except the Cu(II), Pd(II), and Au(III) complexes. The participation of the thioketo and/or thioenol groups, in addition to the pyridyl nitrogen, has been confirmed in the latter three complexes. The role of the methyl groups in positions 4 and 6 as well as the pH of the reaction mixture has been investigated. Also, the effect of anions (Cl- and OAc-) attached to the metal salts on the structure of the complexes has been studied. The stereochemistry of the metal complexes has been determined from spectral (IR, UV-Vis., H-1 NMR and mass) and magnetic measurements. The results suggest a square-planar geometry for the Pd(II) and Au(III) complexes, a tetrahedral structure for one of the Co(II) complexes and octahedral geometry for the other metal complexes. The amount of solvents inside or outside the coordination sphere has been determined using TGA and DTA measurements.

  DOI：

  10.1081/sim-100104788