((2-cyclopentadienylethyl)dimethylamine)(2,3-dimethylbut-2-en-1,4-diyl)scandium | 625080-49-1

• 英文名称: ((2-cyclopentadienylethyl)dimethylamine)(2,3-dimethylbut-2-en-1,4-diyl)scandium
• CAS: 625080-49-1
• 化学式: C₁₅H₂₄NSc
• 分子量: 263.318
• InChiKey: GVDUOJBPKNLQFA-XRPAZMCKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  ((2-cyclopentadienylethyl)dimethylamine)(2,3-dimethylbut-2-en-1,4-diyl)scandium 、 苯甲腈 以 not given 为溶剂， 生成 [(C5H4(CH2)2N(methyl)2)Sc(μ2-NC(phenyl)C6H10)]2
  参考文献：
  名称：

  (Cyclopentadienylamine)scandium(2,3-dimethyl-1,3-butadiene):  A 1,3-Diene Complex of Scandium with Sc(I)- and Sc(III)-like Reactivity

  摘要：

  The scandium 2,3-dimethyl-1,3-butadiene complex [eta(5),eta(1)-C5H4(CH2)(2)NMe2]Sc(C6H10) (2) reacts with PhCN via initial nitrile insertion into the Sc-diene bond to give a dimeric mu(2)-imido species, but with a 2,2'-bipyridine via the elimination of the free diene. The latter shows that 2 can be used to generate the reactive fragment [eta(5),eta(1)-C5H4(CH2)(2)NMe2]Sc-I.

  DOI：

  10.1021/om030267h
• 作为产物：
  描述：

  ((2-cyclopentadienylethyl)dimethylamine)scandium dichloride 、 (2,3-dimethyl-1,3-butadiene)Mg*(THF)2 以 乙醚 为溶剂， 以48%的产率得到((2-cyclopentadienylethyl)dimethylamine)(2,3-dimethylbut-2-en-1,4-diyl)scandium
  参考文献：
  名称：

  (Cyclopentadienylamine)scandium(2,3-dimethyl-1,3-butadiene):  A 1,3-Diene Complex of Scandium with Sc(I)- and Sc(III)-like Reactivity

  摘要：

  The scandium 2,3-dimethyl-1,3-butadiene complex [eta(5),eta(1)-C5H4(CH2)(2)NMe2]Sc(C6H10) (2) reacts with PhCN via initial nitrile insertion into the Sc-diene bond to give a dimeric mu(2)-imido species, but with a 2,2'-bipyridine via the elimination of the free diene. The latter shows that 2 can be used to generate the reactive fragment [eta(5),eta(1)-C5H4(CH2)(2)NMe2]Sc-I.

  DOI：

  10.1021/om030267h