[Re(CO)3(tetraphenyldithioimidodiphosphinato)(triphenylphosphine)] | 1370508-98-7

• 英文名称: [Re(CO)3(tetraphenyldithioimidodiphosphinato)(triphenylphosphine)]
• 英文别名: [Re(CO)3(PPh3)(Ph2P(S)NP(S)Ph2-κ2S)]
• CAS: 1370508-98-7
• 化学式: C₄₅H₃₅NO₃P₃ReS₂
• 分子量: 981.038
• InChiKey: ISYBKCURWYIGBQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (tetracarbonyl)(tetraphenyl-imidodithiophosphinato-κ2Se,Se')rhenium 、 三苯基膦 以 甲苯 为溶剂， 以97%的产率得到[Re(CO)3(tetraphenyldithioimidodiphosphinato)(triphenylphosphine)]
  参考文献：
  名称：

  Synthetic and structural studies of phosphorus carbonyl rhenacycles containing the tetraphenyldithioimidodiphosphinato ligand

  摘要：

  The synthesis of rhenacycles [Re(CO)(3)(L){Ph2P(S)NP(S)Ph-2-kappa S-2}] L = PPh3, (1), PMePh2 (2), PMe2Ph, (3), and PMe3, (4) by a straightforward high yield procedure is described. All new inorganic complexes (1)-(4) were characterized in solution and in the solid state. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.02.015