[PtCl2(cis-1,3-bis(diphenylphosphino)indan)] | 777063-72-6

• 英文名称: [PtCl2(cis-1,3-bis(diphenylphosphino)indan)]
• CAS: 777063-72-6
• 化学式: C₃₃H₂₈Cl₂P₂Pt
• 分子量: 752.519
• InChiKey: AQIUWPBVTFLZOZ-KLNJLLCTSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  dichloro( 1,5-cyclooctadiene)platinum(ll) 、 1,3-bis(diphenylphosphino)indan (anphos) 以 二氯甲烷 为溶剂， 以36.3%的产率得到[PtCl2(cis-1,3-bis(diphenylphosphino)indan)]
  参考文献：
  名称：

  Chelates formed by a constrained bis(diphenylphosphino)xylene; the crystal structures of [FeCl2(anphos)] and [RhCl(CO)(anphos-monoxide)]

  摘要：

  The indan derived diphosphine, cis-1,3-(diphenylphosphino)indan (anphos) is synthesised by the addition of Ph2P(BH3)Li to cis-1,3-dibromoindan followed by deprotection with diethylamine. Anphos readily forms the bicyclic chelates [RhCl(CO)(anphos)], [PtCl2(anphos)], [PtCl(Me)(anphos)] and [FeCl2(anphos)]. The crystal structures of [FeCl2(anphos)] and the monoxide complex, [RhCl(CO)(anphosO)] have been determined. Reaction of the diphosphine with [Rh(acac)(CO)(2)] under moderate hydroformylation conditions catalysed the formation of 1- heptanal and branched aldehydes from 1-hexene in a ratio of 1.5:1. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.06.022