1-氯-4-(2-甲基庚基)苯 | 1205517-10-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1-氯-4-(2-甲基庚基)苯
• 英文名称: 1-chloro-4-(2-methylheptyl)benzene
• CAS: 1205517-10-7
• 化学式: C₁₄H₂₁Cl
• 分子量: 224.774
• InChiKey: JEWGSCVSTVJYJT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  15
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  tris(2-methylheptyl)indium 、 chlorobenzene,chlorozinc(1+) 在 palladium chloride*2MeCN 、 2-氯-2-苯基苯乙酮 、 双(2-二苯基磷苯基)醚 作用下， 以 四氢呋喃 为溶剂， 反应 5.0h， 以75%的产率得到1-氯-4-(2-甲基庚基)苯
  参考文献：
  名称：

  高选择性钯催化氧化C sp 2 C sp 3通过双金属转移作用交叉偶联芳基锌和烷基铝试剂

  摘要：

  Abstractmagnified imageUsing desyl chloride (2‐chloro‐1,2‐diphenylethanone) as the oxidant, the palladium‐catalyzed reaction of arylzinc with alkylindium reagents occurred smoothly in a highly selective manner to afford the products in 57–90% yields. Preliminary kinetic data indicated that alkylindium reagents were highly favored for transmetallation with the alkoxy‐palladium moiety.

  DOI：

  10.1002/adsc.200800703

文献信息

• Herbicides
  申请人：SYNGENTA PARTICIPATIONS AG

  公开号：US11230538B2

  公开（公告）日：2022-01-25

  The present invention relates to herbicidally active pyridino-/pyrimidino-pyridine derivatives. The invention further provides processes and intermediates used for the preparation of such derivatives. The invention further extends to herbicidal compositions comprising such derivatives, as well as to the use of such compounds and compositions in controlling undesirable plant growth: in particular the use in controlling weeds, in crops of useful plants.

  本发明涉及具有除草活性的吡啶/嘧啶-吡啶衍生物。本发明进一步提供了用于制备此类衍生物的工艺和中间体。本发明还涉及包含此类衍生物的除草组合物，以及此类化合物和组合物在控制植物不良生长方面的用途：特别是在控制有用植物作物中的杂草方面的用途。
• HERBICIDES
  申请人：SYNGENTA PARTICIPATIONS AG

  公开号：US20190330179A1

  公开（公告）日：2019-10-31

  The present invention relates to herbicidally active pyridino-/pyrimidino-pyridine derivatives. The invention further provides processes and intermediates used for the preparation of such derivatives. The invention further extends to herbicidal compositions comprising such derivatives, as well as to the use of such compounds and compositions in controlling undesirable plant growth: in particular the use in controlling weeds, in crops of useful plants.