[Zn(μ-NC(N(Et)2)(NC4H8))(N(SiMe3)2)]2 | 1000163-79-0

• 英文名称: [Zn(μ-NC(N(Et)2)(NC4H8))(N(SiMe3)2)]2
• 英文别名: [Zn(μ-DEPYRG)(N(SiMe3)2)]2；[Zn(μ-PYRDEG)(N(SiMe3)2)]2
• CAS: 1000163-79-0
• 化学式: C₃₀H₇₂N₈Si₄Zn₂
• 分子量: 788.077
• InChiKey: YBYCZKOEVDHSFF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  乙醇 、 [Zn(μ-NC(N(Et)2)(NC4H8))(N(SiMe3)2)]2 、 2,6-二叔丁基-4-甲基苯酚 以 正己烷 为溶剂， 以29%的产率得到[zinc(μ-OEt)(4-Me-2.6-(tBu)2-C6H2O)(HNC(NC4H8)(N(Et)2))]2
  参考文献：
  名称：

  A Family of 1,1,3,3‐Tetraalkylguanidine (H‐TAG) Solvated Zinc Aryloxide Precatalysts for the Ring‐Opening Polymerization of rac ‐Lactide

  摘要：

  AbstractReaction of [Zn(μ‐TAG){N(SiMe3)2}]2 {TAG = N=C[N(CH2CH3)2N(CH3)2] (DEDMG), N=C{[NCH2CH2CH2CdH2(N–Cd)]N(CH2CH3)2} (DEPYRG) and N=C{[NCH2CH2CH2CH2CeH2(N–Ce)]N(CH2CH3)2} (DEPIPG)} with 2 equiv. of ethanol (EtOH) and 2 equiv. of HOAr {OAr = OC6H3(CMe3)‐2‐(CH3)‐6 (BMP) or OC6H2[C(CH3)3]2‐2,6‐(CH3)‐4 (4MeDBP)} results in dizinc alkoxides with the general formula [Zn(μ‐OEt)(OAr)(H‐TAG)]2 (1–3). Et2Zn was additionally treated with 2 equiv. of 1,1,3,3‐tetramethylguanidine (H‐TMG) and H‐BMP or HOC6H3(C6H5)2‐2,6 to yield [Zn(BMP)2(H‐TMG)2] (4) and [Zn{OC6H3(C6H5)2‐2,6}2(H‐TMG)2] (5). Complexes 1, 2, 4, and 5 were characterized by single‐crystal X‐ray diffraction. Polymerization of rac‐lactide with 1–5 and [Zn(μ‐OMe)(4MeDBP)(H‐TMG)]2 (6) were found to generate polylactide (PLA). The bulk powders for all complexes were found to be in agreement with the crystal structures based on elemental analyses, FTIR spectroscopy, and 1H and 13C NMR spectroscopic studies.

  DOI：

  10.1002/ejic.200900986
• 作为产物：
  描述：

  四氢吡咯 、 N-氰基二乙基胺 、 zinc(II) chloride 、 lithium hexamethyldisilazane 在 n-BuLi 作用下， 以 乙醚 、 正己烷 为溶剂， 以34%的产率得到[Zn(μ-NC(N(Et)2)(NC4H8))(N(SiMe3)2)]2
  参考文献：
  名称：

  Synthesis and characterization of a series of zinc complexes stabilized by 1,1,3,3-tetraalkylguanidinate (TAG) ligands: [Zn(μ-TAG){N(SiMe3)2}]2

  摘要：

  A series of novel structurally varied low-coordinate zinc complexes utilizing 1,1,3,3-tetraalkylguanidinate (TAG) ligands were synthesized and characterized. Li(TAG) and lithium bis-trimethylsilylamide, LiN(SiMe3)(2), were successfully reacted with ZnCl2 in a 1:1 ratio to yield the corresponding dinuclear complexes with the general formula [Zn(mu-TAG) {N(SiMe3)(2)}](2), where[GRAPHICS]and[GRAPHICS]Compounds 1-6 were characterized by single-crystal X-ray diffraction. The bulk powders for all complexes were found to be in agreement with the crystal structures based on elemental analyses, FT-IR spectroscopy, and H-1 and C-13 NMR studies. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.08.013