[ReBr(CO)3(bis(diethylamino)methane)] | 1147421-26-8

• 英文名称: [ReBr(CO)3(bis(diethylamino)methane)]
• CAS: 1147421-26-8
• 化学式: C₁₂H₂₂BrN₂O₃Re
• 分子量: 508.429
• InChiKey: KJMNGSJIGBRGJR-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  五羰基溴铼(I) 、 N,N,N',N'-四乙基甲二胺 以 甲苯 为溶剂， 以46%的产率得到[ReBr(CO)3(bis(diethylamino)methane)]
  参考文献：
  名称：

  Synthesis of alkynyl(tricarbonyl)rhenium complexes containing a lightly coordinated diamine ligand

  摘要：

  Several alkynyl(tricarbonyl)diaminerhenium complexes were prepared from corresponding halo complexes and silver acetylides. With the diamine N,N'-dimethylpiperazine the compounds were found to be sufficiently stable to allow synthetic transformations on the acetylide ligand as well as purification by chromatography and subsequent substitution of the diamine ligand by stronger ligands such as phenanthrolines or isocyanides. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.07.031