2,6-bis(1-(3-propylsulfonate)benzimidazol-2'-yl)pyridine | 1319258-45-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: 2,6-bis(1-(3-propylsulfonate)benzimidazol-2'-yl)pyridine
• 英文别名: 3-[2-[6-[1-(3-Sulfopropyl)benzimidazol-2-yl]pyridin-2-yl]benzimidazol-1-yl]propane-1-sulfonic acid
• CAS: 1319258-45-1
• 化学式: C₂₅H₂₅N₅O₆S₂
• 分子量: 555.635
• InChiKey: NFZMSECEOVDMIT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  38
• 可旋转键数：
  10
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  174
• 氢给体数：
  2
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  potassium tetrachloroplatinate(II) 、 2,6-bis(1-(3-propylsulfonate)benzimidazol-2'-yl)pyridine 以 二甲基亚砜 为溶剂， 以57%的产率得到
  参考文献：
  名称：

  Supramolecular Self-Assembly of Amphiphilic Anionic Platinum(II) Complexes: A Correlation between Spectroscopic and Morphological Properties

  摘要：

  A new class of amphiphilic anionic platinum(II) bzimpy complexes has been demonstrated to show aggregation in water through Pt center dot center dot center dot Pt and pi-pi stacking interactions. An interesting aggregation-partial deaggregation-aggregation process and a morphological transformation from vesicles to nanofibers have been demonstrated. These changes can be systematically controlled by the variation of solvent composition and could readily be probed by UV-vis absorption, emission, NMR, transmission electron microscopy, and even with our naked eyes.

  DOI：

  10.1021/ja203920w