(κ2-1,1'-bis(diphenylphosphino)ferrocene)bis(5-phenyl-1,3,4-oxadiazole-3-thionate)palladium(II) | 1381991-55-4

• 英文名称: (κ2-1,1'-bis(diphenylphosphino)ferrocene)bis(5-phenyl-1,3,4-oxadiazole-3-thionate)palladium(II)
• CAS: 1381991-55-4
• 化学式: C₅₀H₃₈FeN₄O₂P₂PdS₂
• 分子量: 1015.22
• InChiKey: CFKJQJXWUMXMKC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 、 potassium 5-phenyl-1,3,4-oxadiazole-2-thiolate 以 乙醇 、 氯仿 为溶剂， 以86%的产率得到(κ2-1,1'-bis(diphenylphosphino)ferrocene)bis(5-phenyl-1,3,4-oxadiazole-3-thionate)palladium(II)
  参考文献：
  名称：

  Heteroleptic palladium(II) and platinum(II) complexes of 1,1-bis(diphenylphosphino)ferrocene (dppf) and heterocyclic thionates: Crystal structures of [Pt(Phozt)2(κ2-dppf)] (PhoztH=5-phenyl-1,3,4-oxadiazole-2-thione) and [Pd(bzoxt)2(κ2-dppf)] (bzoxtH=benz-1,3-oxazoline-2-thione)

  摘要：

  Treatment of [MCl2(kappa(2)-dppf)] (M = Pd or Pt) with two equivalents of potassium heterocyclic thionate salts (KL) affords mixed ligand complexes [ML2(kappa(2)-dppf)] [L = 5-phenyl-1,3,4-oxadiazole-2-thionate (Phozt), 4,5-diphenyl-1,2,4-triazole-3-thionate (Ph(2)tzt), benz-1,3-thiazoline-2-thionate (bztzt) and benz-1,3-oxazoline-2-thionate (bzoxt)]. X-ray structures of two examples, [Pt(Phozt)(2)(kappa(2)-dppf)] and [Pd(bzoxt)(2)(kappa(2)-dppf)], show that the ligands are coordinated in a monodentate fashion via the sulfur atom. (c) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.04.007