(1S,4S,5R,8R)-1-Methyl-3-oxo-4-(2-phenoxy-acetylamino)-2-oxa-6-thia-9-aza-bicyclo[3.2.2]nonane-8-carboxylic acid 2,2,2-trichloro-ethyl ester | 34069-14-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: (1S,4S,5R,8R)-1-Methyl-3-oxo-4-(2-phenoxy-acetylamino)-2-oxa-6-thia-9-aza-bicyclo[3.2.2]nonane-8-carboxylic acid 2,2,2-trichloro-ethyl ester
• CAS: 34069-14-2
• 化学式: C₁₈H₁₉Cl₃N₂O₆S
• 分子量: 497.784
• InChiKey: AWXCOOBUIPMUEO-UMPJEAMMSA-N

反应信息

• 作为产物：
  描述：

  (6R)-3t-hydroxy-3c-methyl-8-oxo-7t-(2-phenoxy-acetylamino)-(6rH)-5-thia-1-aza-bicyclo[4.2.0]octane-2c-carboxylic acid 2,2,2-trichloro-ethyl ester 在 silica gel 作用下， 生成 (1S,4S,5R,8R)-1-Methyl-3-oxo-4-(2-phenoxy-acetylamino)-2-oxa-6-thia-9-aza-bicyclo[3.2.2]nonane-8-carboxylic acid 2,2,2-trichloro-ethyl ester
  参考文献：
  名称：

  The determination of stereochemistry and reactions of 3-hydroxy, 3-methyl cephalosporins

  摘要：

  DOI：

  10.1016/s0040-4039(01)97197-7