N,N'-(ferrocene-1,1'-diyldimethylylidene)di(3,4,5-trichloroaniline) | 947280-86-6

• 英文名称: N,N'-(ferrocene-1,1'-diyldimethylylidene)di(3,4,5-trichloroaniline)
• CAS: 947280-86-6
• 化学式: C₂₄H₁₄Cl₆FeN₂
• 分子量: 598.954
• InChiKey: RTCOUDIHKIKHJA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,1'-二茂铁二甲醛 、 3,4,5-三氯苯胺 以 neat (no solvent, solid phase) 为溶剂， 以74%的产率得到N,N'-(ferrocene-1,1'-diyldimethylylidene)di(3,4,5-trichloroaniline)
  参考文献：
  名称：

  Further solvent-free reactions of ferrocenylaldehydes: Synthesis of 1,1′-ferrocenyldiimines and ferrocenylacrylonitriles

  摘要：

  Grinding of 1, 1 '-ferrocenedicarboxaldehyde with a 2.2 molar equivalent of an aromatic amine in a solvent-free environment provided excellent yields of 1, 1 '-ferrocenyldiimines. After mixing the aldehyde and amines, a gum or melt formed which eventually solidified to the product. An analytically pure sample of the product was obtained by cold recrystallization. Grinding of ferrocenecarboxaldehyde and 4-substituted phenylacetonitriles under solvent-free conditions provided good yields of the corresponding ferrocenylacrylonitriles. The yield in this reaction was very low when the substituent group para to the acetonitrile group was electron-donating. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.04.011