2,2-dimethyl-N-phenyl-1-phenylphosphanylpropan-1-imine | 68971-43-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2-dimethyl-N-phenyl-1-phenylphosphanylpropan-1-imine
• CAS: 68971-43-7
• 化学式: C₁₇H₂₀NP
• 分子量: 269.326
• InChiKey: XOBHVJMJPIOAIS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  12.4
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2,2-dimethyl-N-phenyl-1-phenylphosphanylpropan-1-imine 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 生成 N,N′-((phenylphosphinediyl)bis(2,2-dimethylpropan-1-yl-1-ylidene))dianiline
  参考文献：
  名称：

  双（亚氨基）膦：合成与配位化学

  摘要：

  Bis(imino)phosphanes can be synthesized efficiently from iminophosphanes and nitrilium triflates, allowing for nonsymmetric substitution at the imine groups. Symmetrically substituted derivatives can even be obtained in a One-pot procedure from primary phosphanes. These potential N,N-bidentate ligands are sensitive toward Cu(II), Zn(II), and rhodium(I) sources, resulting in loss of an imine group. For [RhCl(COD)](2) this led to an N,P- and P-Ohelating bimetallic complex. Bis(imino)phosphanes with C -Me substituents rearrange in situ to unique 1,3,5-phosphadiazapentadienes for which a P-coordinated gold(I) complex is repotted. The bis(imino)phosphanes ate readily oxidized to stable bis(imino)phosphane oxides with aqueous H2O2.

  DOI：

  10.1021/acs.organomet.6b00063
• 作为产物：
  描述：

  (N-phenyl)(tert-butyl)carbonitrilium triflate 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 生成 2,2-dimethyl-N-phenyl-1-phenylphosphanylpropan-1-imine
  参考文献：
  名称：

  双（亚氨基）膦：合成与配位化学

  摘要：

  Bis(imino)phosphanes can be synthesized efficiently from iminophosphanes and nitrilium triflates, allowing for nonsymmetric substitution at the imine groups. Symmetrically substituted derivatives can even be obtained in a One-pot procedure from primary phosphanes. These potential N,N-bidentate ligands are sensitive toward Cu(II), Zn(II), and rhodium(I) sources, resulting in loss of an imine group. For [RhCl(COD)](2) this led to an N,P- and P-Ohelating bimetallic complex. Bis(imino)phosphanes with C -Me substituents rearrange in situ to unique 1,3,5-phosphadiazapentadienes for which a P-coordinated gold(I) complex is repotted. The bis(imino)phosphanes ate readily oxidized to stable bis(imino)phosphane oxides with aqueous H2O2.

  DOI：

  10.1021/acs.organomet.6b00063