4,6-二溴-3-氟-2-(1-(2-乙基己酮))-噻吩并[3,4-B]噻吩 | 1352743-83-9

• 物质功能分类: 医药中间体 - 噻吩类化合物
• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 4,6-二溴-3-氟-2-(1-(2-乙基己酮))-噻吩并[3,4-B]噻吩
• 中文别名: 1-(4,6-二溴-3-氟噻吩并[3,4-b]噻吩-2-基)-2-乙基-1-己酮
• 英文名称: 1-(4,6-Dibromo-3-fluorothieno[3,4-b]thiophen-2-yl)-2-ethylhexan-1-one
• 英文别名: 1-(4,6-dibromo-3-fluorothieno[2,3-c]thiophen-2-yl)-2-ethylhexan-1-one
• CAS: 1352743-83-9
• 化学式: C₁₄H₁₅Br₂FOS₂
• 分子量: 442.2
• InChiKey: CPRHXJNYCFYUPG-UHFFFAOYSA-N

物化性质

• 沸点：
  459.1±40.0 °C(Predicted)
• 密度：
  1.637±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.6
• 重原子数：
  20
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  73.6
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• ORGANIC SEMICONDUCTOR COMPOUND, METHOD FOR PREPARING SAME, AND ORGANIC SEMICONDUCTOR DEVICE EMPLOYING SAME
  申请人：Moon Sang Jin

  公开号：US20140046013A1

  公开（公告）日：2014-02-13

  Provided are an organic semiconductor compound, a method for preparing same, a polymer compound having the organic semiconductor compound of the present invention as a monomer, and an organic semiconductor device containing the polymer compound. Said organic semiconductor compound has side chains in the chemical structure thereof, and is highly soluble in a solvent, and therefore the organic semiconductor compound can be effectively used in solution-based processes. The organic semiconductor device containing the polymer compound according to the present invention yields high manufacturing efficiency

  提供了一种有机半导体化合物、其制备方法、以该有机半导体化合物为单体的聚合物化合物以及含有该聚合物化合物的有机半导体器件。该有机半导体化合物在其化学结构中具有侧链，并且在溶剂中高度溶解，因此该有机半导体化合物可以有效地用于溶液基工艺。根据本发明的聚合物化合物所含有的有机半导体器件具有高制造效率。
• SYNTHESIS OF PHOTOVOLTAIC CONJUGATED POLYMERS
  申请人：Solarmer Energy, Inc.

  公开号：US20130214213A1

  公开（公告）日：2013-08-22

  A method of making a fluorothieno[3,4-b]thiophene derivatives and photovoltaic polymers containing same using 3-bromothiophene-2-carboxylic acid as a starting material. This synthetic route provides an easier synthesis as well as greater yield and a purer product, which produces superior results over the prior art less pure products. The resulting materials can be used in a variety of photovoltaic applications and devices, especially solar cells.

  一种制备氟噻吩[3,4-b]噻吩衍生物和含有该衍生物的光伏聚合物的方法，使用3-溴噻吩-2-羧酸作为起始材料。该合成路线提供了更简单的合成方法以及更高的产量和更纯的产物，相比之前的不纯产物，产生了更优异的结果。所得材料可用于各种光伏应用和设备，特别是太阳能电池。
• PROCESS OF PRODUCING AND APPLICATIONS OF THREE COMPONENT BENZO[1,2-B:4,5-B] DITHIOPHENE-THIENOTHIOPHENE RANDOMLY SUBSTITUTED POLYMERS FOR ORGANIC SOLAR CELLS
  申请人：PHILLIPS 66 COMPANY

  公开号：US20150349259A1

  公开（公告）日：2015-12-03

  A process of polymerizing f with wherein the stoichiometric ratio of f≈(g+h) and f, g and h are not equal to 0. This process can also have R1 selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof. Additionally, x and y can be different from each other and can be independently selected from the group consisting of: alkyl group, alkoxy group, aryl groups, where y=1-3, where y=0-12, where R2 is selected from the group consisting of H, alkyl group, alkoxy group, aryl groups, where R3 is selected from the group consisting of H, alkyl group, alkoxy group, aryl groups, where R4 and R5 are independently selected from the group consisting of H, alkyl group, alkoxy group, aryl groups, —NR 6 R 7 where R6 and R7 are independently selected from the group consisting of H, alkyl group, alkoxy group, aryl groups.
• PROCESS OF MANUFACTURING AND APPLICATIONS OF A MULTI-COMPONENT BENZO[1,2-B:4,5-B] DITHIOPHENE-THIENOTHIOPHENE RANDOMLY SUBSTITUTED CONJUGATED POLYMERS FOR ORGANIC SOLAR CELLS
  申请人：PHILLIPS 66 COMPANY

  公开号：US20150344616A1

  公开（公告）日：2015-12-03

  A process of polymerizing wherein the stoichiometric ratio of (f+g)≈(h+i) and f, g, h and i are not equal to 0. Additionally, R1, R2, R3 and R4 can be independently selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof and where the combination of R1, R2, R3 and R4 are not all identical. In addition, x and y can be different from each other and independently selected from the group consisting of: alkyl group, alkoxy group, aryl groups, where y=1-3, where y=0-12, where R5 is selected from the group consisting of H, alkyl group, alkoxy group, aryl groups, where R6 is selected from the group consisting of H, alkyl group, alkoxy group, aryl groups, where R7 and R8 are independently selected from the group consisting of H, alkyl group, alkoxy group, aryl groups, —NR 9 R 10 where R9 and R10 are independently selected from the group consisting of H, alkyl group, alkoxy group, aryl groups.
• POLYMER AND SOLAR CELL USING THE SAME
  申请人：KABUSHIKI KAISHA TOSHIBA

  公开号：US20160099414A1

  公开（公告）日：2016-04-07

  In one embodiment, a polymer includes a repeating unit represented by a formula (1) shown below. A weight-average molecular weight of the polymer is in a range of 3000 or more to 1000000 or less. R1 indicates a monovalent group selected from hydrogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aromatic group, and a substituted or unsubstituted hetero-aromatic group. R2, R3, and R4 indicate independently a monovalent group selected from hydrogen, halogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aromatic group, and a substituted or unsubstituted hetero-aromatic group. X, Y, and Z indicate independently an atom selected from O, S, and Se.