[(Re(O)Cl(3,5-dimethylpyrazole)3)(μ-O)(Re(O)Cl3(3,5-dimethylpyrazole))] * 0.87 (CH2Cl2) | 221130-53-6

• 英文名称: [(Re(O)Cl(3,5-dimethylpyrazole)3)(μ-O)(Re(O)Cl3(3,5-dimethylpyrazole))] * 0.87 (CH2Cl2)
• 英文别名: [(Re(O)Cl2(3,5-dimethylpyrazole)2)(μ-O)(Re(O)Cl2(3,5-dimethylpyrazole)2)] * CH2Cl2
• CAS: 221130-53-6
• 化学式: 0CH₂Cl₂*C₂₀H₃₂Cl₄N₈O₃Re₂
• 分子量: 1020.64
• InChiKey: DABSDTNFCZWPQL-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tetra-n-butylammonium tetrachlorooxorhenate(V) 、 三(3,5-二甲基-1-吡唑基)硼氢化钾 以 四氢呋喃 为溶剂， 生成 [(Re(O)Cl(3,5-dimethylpyrazole)3)(μ-O)(Re(O)Cl3(3,5-dimethylpyrazole))] * 0.87 (CH2Cl2) 、 [(Re(O)Cl(3,5-dimethylpyrazole)3)(μ-O)(Re(O)Cl3(3,5-dimethylpyrazole))] * 0.87 (CH2Cl2)
  参考文献：
  名称：

  Deboronation of HB(3,5-Me2C3HN2)3− in a reaction with [Re(O)Cl4]−, the X-ray crystal structures of [{Re(O)Cl(3,5-Me2C3HN2H)3}(μ-O){Re(O)Cl3(3,5-Me2C3HN2H)}] and [{Re(O)Cl2(3,5-Me2C3HN2H)2}(μ-O){Re(O)Cl2(3,5-Me2C3HN2H)2}]

  摘要：

  A modified synthetic route to [Re(O)(tp*)Cl-2] {tp* =HB(3.5-Me2C3HN2)(3)} from Re2O7 is described. The reaction between Bu4N[Re(O)Cl-4] and Ktp* affords, as its main product, the unsymmetrically substituted binuclear ore-bridged complex [{Re(O)Cl(3,5Me(2)C(3)HN(2)H)(3)}(mu-O) {Re(O)Cl-3(3,5-Me2C3HN2H)}] (1) together with some of the known symmetrically substituted isomer [{Re(O)Cl-2(3,5-Me2C3HN2H)(2)}(mu-O) {Re(O)Cl-2(3.5-Me2C3HN2H)(2)}] (2). Both isomers were characterised by single crystal X-ray diffraction studies of the CH2Cl2 solvates. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00305-3