1-tert-Butoxycarbonyloxy-2,2,6,6-tetramethylpiperidin-4-yl Benzoate | 376587-87-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-tert-Butoxycarbonyloxy-2,2,6,6-tetramethylpiperidin-4-yl Benzoate
• 英文别名: [2,2,6,6-tetramethyl-1-[(2-methylpropan-2-yl)oxycarbonyloxy]piperidin-4-yl] benzoate
• CAS: 376587-87-0
• 化学式: C₂₁H₃₁NO₅
• 分子量: 377.481
• InChiKey: KIYZQPUNFNUQIM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  27
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  65.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  1-hydroxy-2,2,6,6-tetramethylpiperidin-4-yl benzoate 、 二碳酸二叔丁酯 在 4-二甲氨基吡啶 作用下， 以 四氢呋喃 为溶剂， 反应 30.0h， 以gives 6.2 g (66%) of the compound 115, which的产率得到1-tert-Butoxycarbonyloxy-2,2,6,6-tetramethylpiperidin-4-yl Benzoate
  参考文献：
  名称：

  Process for reducing the molecular weight of polypropylene

  摘要：

  本发明涉及选自HALS（立体位阻胺）化合物组和新型羟胺酯的已知羟胺酯的使用，用于控制聚丙烯的降解。

  公开号：

  US07030196B2

文献信息

• Hydroxylamine esters as polymerization initiators
  申请人：——

  公开号：US20030216494A1

  公开（公告）日：2003-11-20

  The invention relates to novel cyclic and open-chain hydroxylamine esters and polymerizable compositions comprising these hydroxylamine esters and an ethylenically unsaturated monomer or oligomer. The invention also relates to use as polymerization initiators and to the use of known hydroxylamine esters selected from the group consisting of HALS compounds and the novel hydroxylamine esters for the controlled degradation of polypropylene and for achieving a controlled increase in the molecular weight of polyethylene.

  该发明涉及新型环状和开链羟胺酯以及包括这些羟胺酯和乙烯基不饱和单体或寡聚物的可聚合组合物。该发明还涉及用作聚合引发剂以及用于控制聚丙烯降解和实现聚乙烯分子量控制增加的已知羟胺酯，所述羟胺酯来自HALS化合物和新颖羟胺酯的组合。
• Process for the controlled increase in the molecular weight of polyethylenes
  申请人：Roth Michael

  公开号：US20060128903A1

  公开（公告）日：2006-06-15

  The invention relates to novel cyclic hydroxylamine esters and to the use of known hydroxylamine esters selected from the group consisting of HALS (sterically hindered amine) compounds and the novel hydroxylamine esters achieving a controlled increase in the molecular weight of polyethylene.

  本发明涉及新型环状羟胺酯以及选自包括HALS（立体位阻胺）化合物的已知羟胺酯和实现对聚乙烯分子量的控制增加的新型羟胺酯的使用。
• Hydroxylamine esters as polimerization initiators
  申请人：Ciba Specialty Chemicals Holding Inc.

  公开号：EP1655303A2

  公开（公告）日：2006-05-10

  The invention relates to novel cyclic and open-chain hydroxylamine esters and polymerizable compositions comprising these hydroxylamine esters and an ethylenically unsaturated monomer or oligomer. The invention also relates to use as polymerization initiators and to the use of known hydroxylamine esters selected from the group consisting of HALS compounds and the novel hydroxylamine esters for the controlled degradation of polypropylene and for achieving a controlled increase in the molecular weight of polyethylene.

  本发明涉及新型环状和开链羟胺酯以及包含这些羟胺酯和乙烯基不饱和单体或低聚物的可聚合组合物。本发明还涉及作为聚合引发剂的用途，以及从 HALS 化合物和新型羟胺酯组成的组中选出的已知羟胺酯在聚丙烯受控降解和聚乙烯分子量受控增加方面的用途。
• HYDROXYLAMINE ESTERS AS POLYMERIZATION INITIATORS
  申请人：Ciba Specialty Chemicals Holding Inc.

  公开号：EP1282630A1

  公开（公告）日：2003-02-12
• Process for Reducing the Molecular Weight of Polypropylene Using Hydroxylamine Esters
  申请人：Ciba Specialty Chemicals Holding Inc.

  公开号：EP1282630B1

  公开（公告）日：2006-05-10