m-allyloxyaniline hydrochloride | 102879-28-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: m-allyloxyaniline hydrochloride
• 英文别名: 3-allyloxy-aniline; hydrochloride；3-Allyloxy-anilin; Hydrochlorid；3-allyloxyaniline hydrochloride；3-(Allyloxy)aniline hydrochloride；3-prop-2-enoxyaniline;hydrochloride
• CAS: 102879-28-7
• 化学式: C₉H₁₁NO*ClH
• 分子量: 185.653
• InChiKey: VXFFQUVZYWQDBJ-UHFFFAOYSA-N

物化性质

• 熔点：
  156-157 °C(Solv: acetone (67-64-1))

计算性质

• 辛醇/水分配系数(LogP)：
  2.26
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  35.2
• 氢给体数：
  2
• 氢受体数：
  2

安全信息

• 危险等级：
  IRRITANT
• 海关编码：
  2922299090

反应信息

• 作为反应物：
  描述：

  m-allyloxyaniline hydrochloride 在 三乙胺 作用下， 以 甲醇 、 二氯甲烷 、 甲苯 为溶剂， 反应 24.0h， 生成 4,6-bis{2-[(3-allyloxyphenylimino)methyl]-4-tert-butyl-6-(2-phenylpropan-2-yl) phenoxy}titanium(IV) dichloride
  参考文献：
  名称：

  Design of postmetallocene catalytic systems of arylimine type for olefin polymerization: XIV. Synthesis of (N-Allyloxyaryl)salicylaldimine ligands and their complexes with titanium(IV) dichloride

  摘要：

  By reaction of salicylaldehydes with bulky substituents in the positions 3 and 5 with o-, m-, and p-allyloxyaniline hydrochlorides in the presence of triethylamine a series of the corresponding (N-aryl)-salicylaldimines was obtained, which with TiCl2(OPr-i)(2) afforded complexes of titanium(IV) dichloride L2TiCl2.

  DOI：

  10.1134/s1070428012080076
• 作为产物：
  描述：

  [3-(烯丙氧基)苯基]胺 在 盐酸 作用下， 以 甲醇 、 水 为溶剂， 生成 m-allyloxyaniline hydrochloride
  参考文献：
  名称：

  Design of postmetallocene catalytic systems of arylimine type for olefin polymerization: XIV. Synthesis of (N-Allyloxyaryl)salicylaldimine ligands and their complexes with titanium(IV) dichloride

  摘要：

  By reaction of salicylaldehydes with bulky substituents in the positions 3 and 5 with o-, m-, and p-allyloxyaniline hydrochlorides in the presence of triethylamine a series of the corresponding (N-aryl)-salicylaldimines was obtained, which with TiCl2(OPr-i)(2) afforded complexes of titanium(IV) dichloride L2TiCl2.

  DOI：

  10.1134/s1070428012080076

文献信息

• Self-immobilized catalysts for ethylene polymerization based on various phenoxyimine titanium halide complexes
  作者：N. I. Ivancheva、D. V. Sanieva、S. P. Fedorov、I. V. Oleinik、I. I. Oleinik、G. A. Tolstikov、S. S. Ivanchev

  DOI：10.1007/s11172-012-0116-4

  日期：2012.4

  The kinetic features of ethylene polymerization on ten methylalumoxane-activated self-immobilized bis(phenoxyimine) complexes of titanium chloride of various structure containing oxyallyl functional groups were studied. The catalytic activity of the systems was determined in the temperature range 20–60 °C under ethylene pressure 0.4 MPa. The positions and structures of the oxyallyl group and substituents

  研究了乙烯在十种甲基铝氧烷活化的自固定化双(苯氧基亚胺)配合物上的乙烯聚合动力学特征，该络合物具有各种结构的含氧烯丙基官能团。该系统的催化活性在 20-60°C 的温度范围内和 0.4 MPa 的乙烯压力下测定。配合物的氧烯丙基和苯氧基中的取代基的位置和结构显着改变了基于这些配合物的催化体系的活性、催化剂在聚合物上的自固定速率以及分子量和分子量所得聚乙烯的分布。
• KINASE INHIBITORS AND USES THEREOF
  申请人：Raeppel Stephane

  公开号：US20080255155A1

  公开（公告）日：2008-10-16

  This invention relates to compounds that inhibit protein tyrosine kinase activity. In particular the invention relates to compounds, compositions and methods for the inhibition of kinase activity. The invention also provides compounds, compositions and methods for treating cell proliferative diseases and conditions.

  本发明涉及抑制蛋白酪氨酸激酶活性的化合物。具体而言，本发明涉及抑制激酶活性的化合物、组合物和方法。本发明还提供用于治疗细胞增殖性疾病和病症的化合物、组合物和方法。
• WO2008/46216
  申请人：——

  公开号：——

  公开（公告）日：——
• Specific features of ethylene polymerization on self-immobilizing catalytic systems based on titanium bis(phenoxy imine) complexes
  作者：N. I. Ivancheva、V. K. Badaev、E. V. Sviridova、D. A. Nikolaev、I. V. Oleinik、S. S. Ivanchev

  DOI：10.1134/s1070427211010204

  日期：2011.1

  The kinetics of ethylene polymerization on six methylalumoxane-activated self-immobilizing bis(phenoxy imine) complexes of titanium chloride with allyloxy groups in the m- and p-positions of the N-phenyl ring and with various substituents in the salicylaldehyde fragment was studied. The activity of the complexes in the temperature range 20-60A degrees C and ethylene pressure of 0.4 MPa was evaluated.
• Multicentered self-immobilized ethylene polymerization catalysts based on functionalized titanium halide salicylaldiminate complexes for the synthesis of ultra-high-molecular-weight polyethylene
  作者：N. I. Ivancheva、S. Ya. Khaikin、E. V. Sviridova、S. P. Fedorov、D. V. Sanieva、O. V. Molev、I. V. Oleinik、S. S. Ivanchev

  DOI：10.1134/s1070427212090170

  日期：2012.9

  Specific features of ethylene polymerization using a new group of catalytic systems based on ten methylalumoxane-activated titanium halide salicylaldiminato complexes functionalized with omega-vinylalkoxy groups and containing tert-butyl substituents in the phenoxide moiety were studied. The catalytic activity of the new group of activated complexes is strongly affected by the position of the omega-vinylalkoxy functional group and by the number and position of substituents in the phenoxide moiety. These factors determine the ratio of the homogeneous and heterogeneous steps of the polymerization as a result of the catalyst self-immobilization onto the polymer formed, and also the molecular characteristics of the polymer obtained at 20, 40, and 60 degrees C and ethylene pressure of 0.4 MPa. The possibility and conditions of preparing ultra-high-molecular-weight polyethylene with improved morphology were revealed.