1,2-dihydro-1,2-dihydroxy-7-chloronaphthalene

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,2-dihydro-1,2-dihydroxy-7-chloronaphthalene
• 英文别名: 1,2-Dihydro-1,2-dihydroxy-7-chloronaphthalene；7-chloro-1,2-dihydronaphthalene-1,2-diol
• 化学式: C₁₀H₉ClO₂
• 分子量: 196.633
• InChiKey: BHWDIDIAMZZVQE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,2-dihydro-1,2-dihydroxy-7-chloronaphthalene 在 Escerichia coli recombinant strain JM₁₀₉(pPS₁₇₇₈) 作用下， 以 水 为溶剂， 生成 1,2-dihydroxy-7-chloronaphthalene
  参考文献：
  名称：

  Bioconversion of Substituted Naphthalenes to the Corresponding 1,2-Dihydroxy Derivatives by Escherichia coli Recombinant Strains

  摘要：

  1,2-dihydroxynaphthalenes are produced by bioconversion of the corresponding hydrocarbons using Escherichia coli recombinant strains containing the naphthalene dioxygenase and dehydrogenase genes cloned from Pseudomonas fluorescens N3. Conversions are lead by a two step procedure without isolation of the dihydrodiol intermediate. Conversion rates depend on the position and nature of the naphthalene substituent (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(97)01404-4
• 作为产物：
  描述：

  2-氯萘 在 air 、 Escerichia coli recombinant strain JM₁₀₉(pPS₁₇₇₈) 作用下， 以 水 为溶剂， 生成 1,2-dihydro-1,2-dihydroxy-7-chloronaphthalene
  参考文献：
  名称：

  Bioconversion of Substituted Naphthalenes to the Corresponding 1,2-Dihydroxy Derivatives by Escherichia coli Recombinant Strains

  摘要：

  1,2-dihydroxynaphthalenes are produced by bioconversion of the corresponding hydrocarbons using Escherichia coli recombinant strains containing the naphthalene dioxygenase and dehydrogenase genes cloned from Pseudomonas fluorescens N3. Conversions are lead by a two step procedure without isolation of the dihydrodiol intermediate. Conversion rates depend on the position and nature of the naphthalene substituent (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(97)01404-4