1-(2-硝基-苯基)-芘 | 102442-84-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 中文名称: 1-(2-硝基-苯基)-芘
• 英文名称: 2′-nitrophenyl-1-pyrene
• 英文别名: 1-(2-nitro-phenyl)-pyrene；1-(2-Nitro-phenyl)-pyren；1-(2-Nitrophenyl)pyrene；1-(2-nitrophenyl)pyrene
• CAS: 102442-84-2
• 化学式: C₂₂H₁₃NO₂
• 分子量: 323.351
• InChiKey: RCEARKBWIUHRLU-UHFFFAOYSA-N

物化性质

• 熔点：
  146.5-147.5 °C
• 沸点：
  513.0±19.0 °C(Predicted)
• 密度：
  1.352±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  25
• 可旋转键数：
  1
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  45.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-(2-硝基-苯基)-芘 在 palladium on activated charcoal 、 硫酸 、 溶剂黄146 、 sodium nitrite 作用下， 生成 indeno[1,2,3-de]naphtho[2,1,8-qra]naphthacene-5,16-dione
  参考文献：
  名称：

  675.茚并[ 2,1- a ]环萘的合成

  摘要：

  DOI：

  10.1039/jr9560003487
• 作为产物：
  描述：

  1-溴-2-硝基苯 、 1-芘硼酸 在 四(三苯基膦)钯 potassium carbonate 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 5.0h， 以92%的产率得到1-(2-硝基-苯基)-芘
  参考文献：
  名称：

  Organic light-emitting device

  摘要：

  公开号：

  EP2447250B1

文献信息

• Synthesis, structures and photophysical properties of two regioisomeric phenalenocarbazoles
  作者：Chang-En Luo、Zhe Ding、Xiang-Wen Wu、Zhiqiang Liu

  DOI：10.1016/j.saa.2018.01.004

  日期：2018.4

  have been synthesized by direct reductive cyclization of 2′-Nitrophenyl-pyrene isomers respectively. Their photophysical properties and crystal structures as well as CV properties were investigated and compared with those of sulfur containing analogues. Although the fluorescence emission properties of 1N are very similar with those of 2N, the HOMO energy level of 1N is 0.16 eV higher than that of 2N indicating

  分别通过2'-硝基苯基-py异构体的直接还原环化反应合成了两种区域异构的苯并咔唑。研究了它们的光物理性质和晶体结构以及CV性质，并与含硫类似物进行了比较。虽然荧光发射特性1N是与那些非常相似2N，的HOMO能级1N是0.16 eV的比的更高2N指示1N具有更好的给电子能力。
• ORGANIC LIGHT-EMITTING DEVICE
  申请人：KIM Young-Kook

  公开号：US20120097924A1

  公开（公告）日：2012-04-26

  A heterocyclic compound represented by a general Formula 1 and an organic light-emitting device including the heterocyclic compound. In some embodiments the heterocyclic compound of Formula 1 may be used as a light-emitting material, a hole transporting material, or an electron transporting material. The heterocyclic compound of Formula 1 having a heterocyclic group in the molecules thereof has a high glass transition temperature (Tg) or a high melting point due to the inclusion of the heterocyclic group. Thus, the heterocyclic compound has high heat resistance against Joule's heat generated in an organic layer, between organic layers, or between an organic layer and a metal electrode when light emission occurs, and has high durability in high-temperature environments. An organic light-emitting device manufactured using the heterocyclic compound of Formula 1 has high durability when stored or operated. In addition, due to the inclusion of a substituent such as an aryl group or heteroaryl group, molecular layers formed as thin films may be maintained in good condition, thereby improving the characteristics of the organic light-emitting device.
• US8455867B2
  申请人：——

  公开号：US8455867B2

  公开（公告）日：2013-06-04
• US8546793B2
  申请人：——

  公开号：US8546793B2

  公开（公告）日：2013-10-01