2,2-bis[3-methyl-4-(3-aminophenoxy)phenyl]propane

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2-bis[3-methyl-4-(3-aminophenoxy)phenyl]propane
• 英文别名: 2,2-bis [3-methyl-4-(3-aminophenoxy)phenyl]propane；2,2-bis[4-(3-aminophenoxy)-3-methylphenyl]propane；3-[4-[2-[4-(3-Aminophenoxy)-3-methylphenyl]propan-2-yl]-2-methylphenoxy]aniline
• 化学式: C₂₉H₃₀N₂O₂
• 分子量: 438.569
• InChiKey: QIGZRZPVWRFRJB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  33
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  70.5
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  甲醇 、 1,3-二硝基苯 、 ethyleneglycol monomethylether 、 iron (III) chloride hexahydrate 、 4,4'-(1-甲基亚乙基)双(2-甲基苯酚) 、 甲烷 生成 2,2-bis[3-methyl-4-(3-aminophenoxy)phenyl]propane
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• Bis(3-aminophenoxy) aromatics and method of preparing the same
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0192480A1

  公开（公告）日：1986-08-27

  Bis(3-nitrophenoxy) derivatives of aromatic or bridged aromatic hydrocarbons are derived from m-dinitrobenzene and dihydroxy derivatives of said hydrocarbons by a condensation reaction in dipolar aprotic solvents in the presence of bases. The bis(3-nitrophenoxy) derivatives obtained are successively reduced to afford bis-(3-aminophenoxy) derivatives. This is a new method for reacting the dihydroxy-derivatives with m-dinitrobenzene, and hence can prepare novel bis(3-aminophenoxy) derivatives such as 4,4'-bis(3-aminophenoxy)biphenyl, 1-[4-(3-aminophenoxy) phenyl]-1,3,3-trimethyl-6-(3-aminophenoxy)indan, 6,6'-bis(3-aminophenoxy)-3,3,3',3'-tetramethyl-1,1'spirobiindan, and methyl substituted 2,2'-bis[4-(3-aminophenoxy) phenyl)propane.

  芳香族或桥接芳香族烃的双(3-硝基苯氧基)衍生物是由间二硝基苯和上述烃的二羟基衍生物在碱存在下，在双极性非丙烷溶剂中通过缩合反应制得的。得到的双(3-硝基苯氧基)衍生物被连续还原，得到双(3-氨基苯氧基)衍生物。这是一种将二羟基衍生物与间二硝基苯反应的新方法，因此可以制备新型双（3-氨基苯氧基）衍生物，如 4,4'-双（3-氨基苯氧基）联苯、1-[4-(3-氨基苯氧基)苯基]-1,3,3-三甲基-6-(3-氨基苯氧基)茚，6,6'-双(3-氨基苯氧基)-3,3,3',3'-四甲基-1,1'螺双茚，以及甲基取代的 2,2'-双[4-(3-氨基苯氧基)苯基]丙烷。
• Heat resistant resin composition
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0292243A2

  公开（公告）日：1988-11-23

  Heat resistant resin compositions consisting essentially of 5-95 wt.% of polyimide composed of recurring units represented by the formula (I): wherein X and Y are the same as defined in the claims, and 95-5 wt.% of known aromatic polyetherimide are disclosed. The resin compositions of this invention have good thermal stability in the high temperature region, particularly in the temperature range of 300-400°C. The compositions can be injection molded due to the retention of frictional property in aromatic polyetherimide and also have thermal resistance, impact resistance and abrasion resistance. Therefore the compositions can be widely used as the material of parts in any industrial fields such as automotives, business machines, electric and electronic appliances, automatic energy saving devices, aeronautics and space instruments and general purpose industrial machines, which renders this invention very valuable.

  本发明公开了主要由 5-95 wt.%的由式(I)代表的递归单元组成的聚酰亚胺构成的耐热树脂组合物： 其中 X 和 Y 与权利要求中定义的相同，95-5 重量％的已知芳香族聚醚酰亚胺。 本发明的树脂组合物在高温区，特别是 300-400°C 的温度范围内具有良好的热稳定性。由于保留了芳香族聚醚酰亚胺的摩擦特性，本发明的组合物可以注塑成型，同时还具有耐热性、抗冲击性和耐磨性。因此，本发明的组合物可广泛用作任何工业领域的零件材料，如汽车、商业机械、电子电器、自动节能装置、航空航天仪器和通用工业机械等，因此本发明非常有价值。
• Process for preparing polyimides
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0330505A1

  公开（公告）日：1989-08-30

  A process for preparing a polyimide by reaction of a diamine and a tetracarboxylic dianhydride to obtain a polyamide acid and subjecting the polyamide acid to conversion into a polyimide thermally or chemically. The reaction in the process is carried out in the presence of at least one dicarboxylic anhydride selected from the group consisting of aliphatic dicarboxylic anhydrides and aromatic dicarboxylic anhydrides, and the amount of the tetracarboxylic dianhydride is in the range of from 0.9 to 1.0 mole per mole of the diamine and the amount of the dicarboxylic anhydride is in the range of from 0.001 to 1.0 mole per mole of the diamine. The resultant polyimides exhibit good thermal stability at high temperatures and good forming processability even at low temperatures.

  一种制备聚酰亚胺的工艺，通过二胺和四羧酸二酐反应得到聚酰胺酸，并使聚酰胺酸通过热或化学反应转化为聚酰亚胺。该工艺中的反应是在至少一种选自脂肪族二羧酸酐和芳香族二羧酸酐的二羧酸酐存在下进行的，四羧酸二酐的用量范围为每摩尔二胺 0.9 至 1.0 摩尔，二羧酸酐的用量范围为每摩尔二胺 0.001 至 1.0 摩尔。由此制得的聚酰亚胺在高温下具有良好的热稳定性，即使在低温下也具有良好的成型加工性。
• Process for preparing polyimide having excellent high temperature stability
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0350203A2

  公开（公告）日：1990-01-10

  This invention relates to a process for preparing polyimide having good heat-stability and excellent flowability in a molten state. The polyimide is prepared by reacting 3,3′-diaminobenzophnone or bis(3-aminophenyl)sulfone, tetracarboxylic dianhydrides such as pyromellitic dianhydride, 3,3′,4,4′-benzophenonetetracarboxylic dianhydride and bis(3,4-dicarboxyphenyl) ether dianhydride; and dicarboxylic anhydrides such as glutaric anhydride, 1,2-hexanedicarboxylic anhydride, phthalic anhydride and 3,4-benzophenonedicarboxylic anhydride. The molar ratio of aromatic diamine : tetracarboxylic dianhydride : dicarboxylic anhydride is 1 :(0.9 to 1.0) : (0.001 to 1.0).

  本发明涉及一种在熔融状态下具有良好热稳定性和优异流动性的聚酰亚胺的制备工艺。 这种聚酰亚胺是由 3,3′-二氨基苯甲酮或双(3-氨基苯基)砜、四羧酸二酐（如偏苯三酸酐、3,3′,4,4′-二苯甲酮四羧酸二酐和双(3,4-二羧基苯基)醚二酐）和二羧酸酐（如戊二酸酐、1,1,1,2-二羧酸酐）反应制备的；二羧酸酐，如戊二酸酐、1,2-己二酸酐、邻苯二甲酸酐和 3,4-二苯甲酮二羧酸酐。芳香族二胺：四羧酸二酐：二羧酸酐的摩尔比为 1：（0.9 至 1.0）：（0.001 至 1.0）。
• Polyimide based resin composition
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0430640A1

  公开（公告）日：1991-06-05

  A molding resin composition comprising 99.9 to 50 % by weight of polyimide represented by the formula: and 0.1 to 50 % by weight of polyether ketone resin and/or polyester resin, and more particularly comprising the polyester resin capable of forming an anisotropical molten phase at a temperature of 420 °C or less.

  一种模塑树脂组合物，按重量计由 99.9%至 50%的聚酰亚胺组成，聚酰亚胺由式 和 0.1%至 50%（重量百分比）的聚醚酮树脂和/或聚酯树脂，特别是其中的聚酯树脂能在 420 °C 或更低的温度下形成异向熔融相。